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An iridium complex with an unsupported Ir—Zn bond: diiodido(η(5)-pentamethylcyclopentadienyl)bis(trimethylphosphane)iridiumzinc(Ir—Zn) benzene hemisolvate
The title compound, [IrZnI(2)(C(10)H(15))(C(3)H(9)P)(2)]·0.5C(6)H(6) or [Cp*(PMe(3))(2)Ir]-[ZnI(2)] (Cp* = cyclo-C(5)Me(5)) was obtained and characterized as its benzene solvate [Cp*(PMe(3))(2)Ir]-[ZnI(2)]·0.5C(6)H(6). The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI(2...
Autores principales: | Taullaj, Fioralba, Lough, Alan J., Fekl, Ulrich |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895938/ https://www.ncbi.nlm.nih.gov/pubmed/31871738 http://dx.doi.org/10.1107/S2056989019014622 |
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