Cargando…
Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine
In the title compound, C(20)H(26)N(2)O(9)S, the S atom is attached equatorially to the sugar ring. The C—S bond lengths are unequal, with S—C(s) = 1.8018 (13) Å and S—C(p) = 1.7662 (13) Å (s = sugar and p = pyrimidyl). In the crystal, a system of three weak hydrogen bonds, sharing an oxygen accept...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895939/ https://www.ncbi.nlm.nih.gov/pubmed/31871737 http://dx.doi.org/10.1107/S205698901901449X |
| _version_ | 1783476667798257664 |
|---|---|
| author | Abu-Zaied, Mamdouh A. Elgemeie, Galal H. Jones, Peter G. |
| author_facet | Abu-Zaied, Mamdouh A. Elgemeie, Galal H. Jones, Peter G. |
| author_sort | Abu-Zaied, Mamdouh A. |
| collection | PubMed |
| description | In the title compound, C(20)H(26)N(2)O(9)S, the S atom is attached equatorially to the sugar ring. The C—S bond lengths are unequal, with S—C(s) = 1.8018 (13) Å and S—C(p) = 1.7662 (13) Å (s = sugar and p = pyrimidyl). In the crystal, a system of three weak hydrogen bonds, sharing an oxygen acceptor, links the molecules to form chains propagating parallel to the b-axis direction. |
| format | Online Article Text |
| id | pubmed-6895939 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-68959392019-12-23 Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine Abu-Zaied, Mamdouh A. Elgemeie, Galal H. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(20)H(26)N(2)O(9)S, the S atom is attached equatorially to the sugar ring. The C—S bond lengths are unequal, with S—C(s) = 1.8018 (13) Å and S—C(p) = 1.7662 (13) Å (s = sugar and p = pyrimidyl). In the crystal, a system of three weak hydrogen bonds, sharing an oxygen acceptor, links the molecules to form chains propagating parallel to the b-axis direction. International Union of Crystallography 2019-11-05 /pmc/articles/PMC6895939/ /pubmed/31871737 http://dx.doi.org/10.1107/S205698901901449X Text en © Abu-Zaied et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Abu-Zaied, Mamdouh A. Elgemeie, Galal H. Jones, Peter G. Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title | Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title_full | Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title_fullStr | Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title_full_unstemmed | Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title_short | Crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-O-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| title_sort | crystal structure of 4,6-dimethyl-2-[(2,3,4,6-tetra-o-acetyl-β-d-galactopyranosyl)sulfanyl]pyrimidine |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895939/ https://www.ncbi.nlm.nih.gov/pubmed/31871737 http://dx.doi.org/10.1107/S205698901901449X |
| work_keys_str_mv | AT abuzaiedmamdouha crystalstructureof46dimethyl22346tetraoacetylbdgalactopyranosylsulfanylpyrimidine AT elgemeiegalalh crystalstructureof46dimethyl22346tetraoacetylbdgalactopyranosylsulfanylpyrimidine AT jonespeterg crystalstructureof46dimethyl22346tetraoacetylbdgalactopyranosylsulfanylpyrimidine |