Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)

In the title compound, di-μ-cyanato-1:2κ(2) N:C;2:3κ(2) C:N-di­cyanato-2κ(2) C-bis­(1,4,7,10,13,16-hexa­oxa­cyclo­octa­deca­ne)-1κ(6) O;3κ(6) O-1,3-dipotassium(I)-2-platinum(II), [K(2)Pt(CN)(4)(C(12)H(24)O(6))(2)] or [K(18-crown-6)](2)·[Pt(CN)(4)], two trans-orientated cyano groups of the square-pla...

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Detalles Bibliográficos
Autores principales: Sellin, Malte, Malischewski, Moritz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895955/
https://www.ncbi.nlm.nih.gov/pubmed/31871748
http://dx.doi.org/10.1107/S2056989019015238
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author Sellin, Malte
Malischewski, Moritz
author_facet Sellin, Malte
Malischewski, Moritz
author_sort Sellin, Malte
collection PubMed
description In the title compound, di-μ-cyanato-1:2κ(2) N:C;2:3κ(2) C:N-di­cyanato-2κ(2) C-bis­(1,4,7,10,13,16-hexa­oxa­cyclo­octa­deca­ne)-1κ(6) O;3κ(6) O-1,3-dipotassium(I)-2-platinum(II), [K(2)Pt(CN)(4)(C(12)H(24)O(6))(2)] or [K(18-crown-6)](2)·[Pt(CN)(4)], two trans-orientated cyano groups of the square-planar [Pt(CN)(4)](2−) dianion (Pt site symmetry [Image: see text]) bind to one potassium ion each, which are additionally coordinated by the six O atoms of 18-crown-6. No Pt⋯Pt inter­actions occur in the crystal, but very weak Pt⋯H contacts (2.79 Å) are observed.
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spelling pubmed-68959552019-12-23 Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−) Sellin, Malte Malischewski, Moritz Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, di-μ-cyanato-1:2κ(2) N:C;2:3κ(2) C:N-di­cyanato-2κ(2) C-bis­(1,4,7,10,13,16-hexa­oxa­cyclo­octa­deca­ne)-1κ(6) O;3κ(6) O-1,3-dipotassium(I)-2-platinum(II), [K(2)Pt(CN)(4)(C(12)H(24)O(6))(2)] or [K(18-crown-6)](2)·[Pt(CN)(4)], two trans-orientated cyano groups of the square-planar [Pt(CN)(4)](2−) dianion (Pt site symmetry [Image: see text]) bind to one potassium ion each, which are additionally coordinated by the six O atoms of 18-crown-6. No Pt⋯Pt inter­actions occur in the crystal, but very weak Pt⋯H contacts (2.79 Å) are observed. International Union of Crystallography 2019-11-15 /pmc/articles/PMC6895955/ /pubmed/31871748 http://dx.doi.org/10.1107/S2056989019015238 Text en © Sellin and Malischewski 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Sellin, Malte
Malischewski, Moritz
Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title_full Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title_fullStr Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title_full_unstemmed Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title_short Crystal structure of [K(18-crown-6)](+) (2)[Pt(CN)(4)](2−)
title_sort crystal structure of [k(18-crown-6)](+) (2)[pt(cn)(4)](2−)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895955/
https://www.ncbi.nlm.nih.gov/pubmed/31871748
http://dx.doi.org/10.1107/S2056989019015238
work_keys_str_mv AT sellinmalte crystalstructureofk18crown62ptcn42
AT malischewskimoritz crystalstructureofk18crown62ptcn42

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