(E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis

The title compound, C(14)H(12)BrNO(2), was synthesized by the condensation reaction of 2,3-di­hydroxy­benzaldehyde and 2-bromo-3-methyl­aniline. It crystallizes in the centrosymmetric triclinic space group P [Image: see text]. The configuration about the C=N bond is E. The dihedral angle between the...

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Autores principales: Doğan, Onur Erman, Dege, Necmi, Ağar, Erbil, Fritsky, Igor O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895958/
https://www.ncbi.nlm.nih.gov/pubmed/31871760
http://dx.doi.org/10.1107/S2056989019015718
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author Doğan, Onur Erman
Dege, Necmi
Ağar, Erbil
Fritsky, Igor O.
author_facet Doğan, Onur Erman
Dege, Necmi
Ağar, Erbil
Fritsky, Igor O.
author_sort Doğan, Onur Erman
collection PubMed
description The title compound, C(14)H(12)BrNO(2), was synthesized by the condensation reaction of 2,3-di­hydroxy­benzaldehyde and 2-bromo-3-methyl­aniline. It crystallizes in the centrosymmetric triclinic space group P [Image: see text]. The configuration about the C=N bond is E. The dihedral angle between the planes of the 5-(2-bromo-3-methyl­phenyl ring and the catechol ring is 2.80 (17)°. In the crystal, O—H⋯O hydrogen-bond inter­actions consolidate the crystal packing.
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spelling pubmed-68959582019-12-23 (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis Doğan, Onur Erman Dege, Necmi Ağar, Erbil Fritsky, Igor O. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(14)H(12)BrNO(2), was synthesized by the condensation reaction of 2,3-di­hydroxy­benzaldehyde and 2-bromo-3-methyl­aniline. It crystallizes in the centrosymmetric triclinic space group P [Image: see text]. The configuration about the C=N bond is E. The dihedral angle between the planes of the 5-(2-bromo-3-methyl­phenyl ring and the catechol ring is 2.80 (17)°. In the crystal, O—H⋯O hydrogen-bond inter­actions consolidate the crystal packing. International Union of Crystallography 2019-11-26 /pmc/articles/PMC6895958/ /pubmed/31871760 http://dx.doi.org/10.1107/S2056989019015718 Text en © Doğan et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Doğan, Onur Erman
Dege, Necmi
Ağar, Erbil
Fritsky, Igor O.
(E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title_full (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title_fullStr (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title_full_unstemmed (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title_short (E)-3-{[(2-Bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
title_sort (e)-3-{[(2-bromo-3-methyl­phen­yl)imino]­meth­yl}benzene-1,2-diol: crystal structure and hirshfeld surface analysis
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6895958/
https://www.ncbi.nlm.nih.gov/pubmed/31871760
http://dx.doi.org/10.1107/S2056989019015718
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