Monomeric β‐Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH(2) Groups (E=P, As)

The pnictogenyl Group 13 compounds (Dipp(2)Nacnac)M[E(SiMe(3))(2)]Cl and (Dipp(2)Nacnac)M(EH(2))(2) (Dipp(2)Nacnac=HC[C(Me)N(Ar)](2), Ar: Dipp=2,6‐iPr(2)C(6)H(3); M=Al, Ga, In; E=P, As) were successfully synthesized. The salt metathesis between (Dipp(2)Nacnac)MCl(2) and LiE(SiMe(3))(2) only led to m...

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Detalles Bibliográficos
Autores principales: Li, Bin, Bauer, Susanne, Seidl, Michael, Timoshkin, Alexey Y., Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899646/
https://www.ncbi.nlm.nih.gov/pubmed/31456252
http://dx.doi.org/10.1002/chem.201903887

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