Vinyl Cation Stabilization by Silicon Enables a Formal Metal‐Free α‐Arylation of Alkyl Ketones

The ability of silicon to stabilize vinyl cationic species leads to a redox arylation of alkynes whereby the stringent limitations of reactivity and regioselectivity of alkyl‐substituted alkynes are lifted. This allows the synthesis of a range of α‐silyl‐α′‐arylketones under mild conditions in good...

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Detalles Bibliográficos
Autores principales: Pons, Amandine, Michalland, Jean, Zawodny, Wojciech, Chen, Yong, Tona, Veronica, Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899746/
https://www.ncbi.nlm.nih.gov/pubmed/31638738
http://dx.doi.org/10.1002/anie.201909381

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899746/
https://www.ncbi.nlm.nih.gov/pubmed/31638738
http://dx.doi.org/10.1002/anie.201909381

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