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Ti(3)C(2)-MXene/Bismuth Ferrite Nanohybrids for Efficient Degradation of Organic Dyes and Colorless Pollutants
[Image: see text] The current environmental and potable water crisis requires technological advancement to tackle the issues caused by different organic pollutants. Herein, we report the degradation of organic pollutants such as Congo Red and acetophenone from aqueous media using visible light irrad...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906764/ https://www.ncbi.nlm.nih.gov/pubmed/31858037 http://dx.doi.org/10.1021/acsomega.9b02359 |
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author | Iqbal, M. Abdullah Tariq, Ayesha Zaheer, Ayesha Gul, Sundus Ali, S. Irfan Iqbal, Muhammad Z. Akinwande, Deji Rizwan, Syed |
author_facet | Iqbal, M. Abdullah Tariq, Ayesha Zaheer, Ayesha Gul, Sundus Ali, S. Irfan Iqbal, Muhammad Z. Akinwande, Deji Rizwan, Syed |
author_sort | Iqbal, M. Abdullah |
collection | PubMed |
description | [Image: see text] The current environmental and potable water crisis requires technological advancement to tackle the issues caused by different organic pollutants. Herein, we report the degradation of organic pollutants such as Congo Red and acetophenone from aqueous media using visible light irradiation. To harvest the solar energy for photocatalysis, we fabricated a nanohybrid system composed of bismuth ferrite nanoparticles with two-dimensional (2D) MXene sheets, namely, the BiFeO(3) (BFO)/Ti(3)C(2) (MXene) nanohybrid, for enhanced photocatalytic activity. The hybrid BFO/MXene is fabricated using a simple and low-cost double-solvent solvothermal method. The SEM and TEM images showed that the BFO nanoparticles are attached onto the surface of 2D MXene sheets. The photocatalytic degradation achieved by the hybrid is found to be 100% in 42 min for the organic dye (Congo Red) and 100% for the colorless aqueous pollutant (acetophenone) in 150 min. The BFO/MXene hybrid system exhibited a large surface area of 147 m(2) g(–1) measured via the Brunauer–Emmett–Teller sorption–desorption technique, which is found to be the largest among all BFO nanoparticles and derivatives. The photoluminescence spectra indicate a low electron–hole recombination rate. Fast and efficient degradation of organic molecules is caused by two factors: larger surface area and lower electron–hole recombination rate, which makes the BFO/MXene nanohybrid a highly efficient photocatalyst and a promising candidate for many future applications. |
format | Online Article Text |
id | pubmed-6906764 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-69067642019-12-19 Ti(3)C(2)-MXene/Bismuth Ferrite Nanohybrids for Efficient Degradation of Organic Dyes and Colorless Pollutants Iqbal, M. Abdullah Tariq, Ayesha Zaheer, Ayesha Gul, Sundus Ali, S. Irfan Iqbal, Muhammad Z. Akinwande, Deji Rizwan, Syed ACS Omega [Image: see text] The current environmental and potable water crisis requires technological advancement to tackle the issues caused by different organic pollutants. Herein, we report the degradation of organic pollutants such as Congo Red and acetophenone from aqueous media using visible light irradiation. To harvest the solar energy for photocatalysis, we fabricated a nanohybrid system composed of bismuth ferrite nanoparticles with two-dimensional (2D) MXene sheets, namely, the BiFeO(3) (BFO)/Ti(3)C(2) (MXene) nanohybrid, for enhanced photocatalytic activity. The hybrid BFO/MXene is fabricated using a simple and low-cost double-solvent solvothermal method. The SEM and TEM images showed that the BFO nanoparticles are attached onto the surface of 2D MXene sheets. The photocatalytic degradation achieved by the hybrid is found to be 100% in 42 min for the organic dye (Congo Red) and 100% for the colorless aqueous pollutant (acetophenone) in 150 min. The BFO/MXene hybrid system exhibited a large surface area of 147 m(2) g(–1) measured via the Brunauer–Emmett–Teller sorption–desorption technique, which is found to be the largest among all BFO nanoparticles and derivatives. The photoluminescence spectra indicate a low electron–hole recombination rate. Fast and efficient degradation of organic molecules is caused by two factors: larger surface area and lower electron–hole recombination rate, which makes the BFO/MXene nanohybrid a highly efficient photocatalyst and a promising candidate for many future applications. American Chemical Society 2019-11-25 /pmc/articles/PMC6906764/ /pubmed/31858037 http://dx.doi.org/10.1021/acsomega.9b02359 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Iqbal, M. Abdullah Tariq, Ayesha Zaheer, Ayesha Gul, Sundus Ali, S. Irfan Iqbal, Muhammad Z. Akinwande, Deji Rizwan, Syed Ti(3)C(2)-MXene/Bismuth Ferrite Nanohybrids for Efficient Degradation of Organic Dyes and Colorless Pollutants |
title | Ti(3)C(2)-MXene/Bismuth Ferrite
Nanohybrids for Efficient Degradation of Organic Dyes and Colorless
Pollutants |
title_full | Ti(3)C(2)-MXene/Bismuth Ferrite
Nanohybrids for Efficient Degradation of Organic Dyes and Colorless
Pollutants |
title_fullStr | Ti(3)C(2)-MXene/Bismuth Ferrite
Nanohybrids for Efficient Degradation of Organic Dyes and Colorless
Pollutants |
title_full_unstemmed | Ti(3)C(2)-MXene/Bismuth Ferrite
Nanohybrids for Efficient Degradation of Organic Dyes and Colorless
Pollutants |
title_short | Ti(3)C(2)-MXene/Bismuth Ferrite
Nanohybrids for Efficient Degradation of Organic Dyes and Colorless
Pollutants |
title_sort | ti(3)c(2)-mxene/bismuth ferrite
nanohybrids for efficient degradation of organic dyes and colorless
pollutants |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6906764/ https://www.ncbi.nlm.nih.gov/pubmed/31858037 http://dx.doi.org/10.1021/acsomega.9b02359 |
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