Enhanced Catalytic Hydrogenation Performance of Rh-Co(2)O(3) Heteroaggregate Nanostructures by in Situ Transformation of Rh@Co Core–Shell Nanoparticles

[Image: see text] In this work, poly(vinylpyrrolidone)-stabilized 3–5 nm Rh@Co core–shell nanoparticles were synthesized by a sequential reduction method, which was further in situ transformed into Rh-Co(2)O(3) heteroaggregate nanostructures on alumina supports. The studies of XRD, HAADF-STEM images with phase mappings, XPS, TPR, and DRIFT-IR with CO probes confirm that the as-synthesized Rh@Co nanoparticles were core–shell-like structures with Rh cores and Co-rich shells, and Rh-Co(2)O(3) heteroaggregate nanostructures are obtained by calcination of Rh@Co nanoparticles and subsequent selective H(2) reduction. The Rh-Co(2)O(3)/Al(2)O(3) nanostructures demonstrated enhanced catalytic performance for hydrogenations of various substituted nitroaromatics relative to individual Rh/Al(2)O(3) and illustrated a high catalytic stability during recycling experiments for o-nitrophenol hydrogenation reactions. The catalytic performance enhancement of Rh-Co(2)O(3)/Al(2)O(3) nanocatalysts is ascribed to the Rh-Co(2)O(3) interfaces where the Rh-Co(2)O(3) interaction not only prevents the active Rh particles from agglomeration but also promotes the catalytic hydrogenation performance.