Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters

Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are give...

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Detalles Bibliográficos
Autores principales: Terekhov, V.E., Aleshkevich, V.V., Afanaseva, E.S., Nechausov, S.S., Babkin, A.V., Bulgakov, B.A., Kepman, A.V., Avdeev, V.V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6909154/
https://www.ncbi.nlm.nih.gov/pubmed/31871997
http://dx.doi.org/10.1016/j.dib.2019.104858
Descripción
Sumario:Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are given. Pseudo-first order rate constants are determined for CPP at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation.

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