Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters

Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are give...

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Autores principales: Terekhov, V.E., Aleshkevich, V.V., Afanaseva, E.S., Nechausov, S.S., Babkin, A.V., Bulgakov, B.A., Kepman, A.V., Avdeev, V.V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6909154/
https://www.ncbi.nlm.nih.gov/pubmed/31871997
http://dx.doi.org/10.1016/j.dib.2019.104858
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author Terekhov, V.E.
Aleshkevich, V.V.
Afanaseva, E.S.
Nechausov, S.S.
Babkin, A.V.
Bulgakov, B.A.
Kepman, A.V.
Avdeev, V.V.
author_facet Terekhov, V.E.
Aleshkevich, V.V.
Afanaseva, E.S.
Nechausov, S.S.
Babkin, A.V.
Bulgakov, B.A.
Kepman, A.V.
Avdeev, V.V.
author_sort Terekhov, V.E.
collection PubMed
description Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are given. Pseudo-first order rate constants are determined for CPP at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation.
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spelling pubmed-69091542019-12-23 Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters Terekhov, V.E. Aleshkevich, V.V. Afanaseva, E.S. Nechausov, S.S. Babkin, A.V. Bulgakov, B.A. Kepman, A.V. Avdeev, V.V. Data Brief Chemistry Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are given. Pseudo-first order rate constants are determined for CPP at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation. Elsevier 2019-11-22 /pmc/articles/PMC6909154/ /pubmed/31871997 http://dx.doi.org/10.1016/j.dib.2019.104858 Text en © 2019 The Author(s) http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Chemistry
Terekhov, V.E.
Aleshkevich, V.V.
Afanaseva, E.S.
Nechausov, S.S.
Babkin, A.V.
Bulgakov, B.A.
Kepman, A.V.
Avdeev, V.V.
Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title_full Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title_fullStr Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title_full_unstemmed Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title_short Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
title_sort hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6909154/
https://www.ncbi.nlm.nih.gov/pubmed/31871997
http://dx.doi.org/10.1016/j.dib.2019.104858
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