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Synthesis and Characterization of Allyl Terpene Maleate Monomer
Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower react...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6914792/ https://www.ncbi.nlm.nih.gov/pubmed/31844132 http://dx.doi.org/10.1038/s41598-019-55356-8 |
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author | Gu, Yan Hummel, Matthew Muthukumarappan, Kasiviswanathan Zhao, Zhendong Gu, Zhengrong |
author_facet | Gu, Yan Hummel, Matthew Muthukumarappan, Kasiviswanathan Zhao, Zhendong Gu, Zhengrong |
author_sort | Gu, Yan |
collection | PubMed |
description | Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation. |
format | Online Article Text |
id | pubmed-6914792 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-69147922019-12-18 Synthesis and Characterization of Allyl Terpene Maleate Monomer Gu, Yan Hummel, Matthew Muthukumarappan, Kasiviswanathan Zhao, Zhendong Gu, Zhengrong Sci Rep Article Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation. Nature Publishing Group UK 2019-12-16 /pmc/articles/PMC6914792/ /pubmed/31844132 http://dx.doi.org/10.1038/s41598-019-55356-8 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Gu, Yan Hummel, Matthew Muthukumarappan, Kasiviswanathan Zhao, Zhendong Gu, Zhengrong Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title | Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title_full | Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title_fullStr | Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title_full_unstemmed | Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title_short | Synthesis and Characterization of Allyl Terpene Maleate Monomer |
title_sort | synthesis and characterization of allyl terpene maleate monomer |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6914792/ https://www.ncbi.nlm.nih.gov/pubmed/31844132 http://dx.doi.org/10.1038/s41598-019-55356-8 |
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