Cargando…

Synthesis and Characterization of Allyl Terpene Maleate Monomer

Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower react...

Descripción completa

Detalles Bibliográficos
Autores principales: Gu, Yan, Hummel, Matthew, Muthukumarappan, Kasiviswanathan, Zhao, Zhendong, Gu, Zhengrong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6914792/
https://www.ncbi.nlm.nih.gov/pubmed/31844132
http://dx.doi.org/10.1038/s41598-019-55356-8
_version_ 1783479881759195136
author Gu, Yan
Hummel, Matthew
Muthukumarappan, Kasiviswanathan
Zhao, Zhendong
Gu, Zhengrong
author_facet Gu, Yan
Hummel, Matthew
Muthukumarappan, Kasiviswanathan
Zhao, Zhendong
Gu, Zhengrong
author_sort Gu, Yan
collection PubMed
description Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation.
format Online
Article
Text
id pubmed-6914792
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-69147922019-12-18 Synthesis and Characterization of Allyl Terpene Maleate Monomer Gu, Yan Hummel, Matthew Muthukumarappan, Kasiviswanathan Zhao, Zhendong Gu, Zhengrong Sci Rep Article Terpenes and their derivatives are sustainable, renewable chemicals that can be used as a complementary hydrocarbon. The exceptions are fossil-based feedstocks and lignin-based feedstocks. A simple method has been found to prepare allyl terpene maleate monomer by substitution reaction at lower reaction temperatures. Using terpenes from turpentine, maleic anhydride and allyl chloride as reactants, the synthesized monomer, terpene-diallyl maleate adduct, was prepared by D-A addition, hydrolysis, and substitution reaction. The resultant monomer was characterized for the first time. The synthesized product will be a versatile monomer and a very important intermediate, having broad application prospects. The synthesized monomer will replace similar aromatic compounds in certain applications because of its low-toxicity and sustainability. The synthesized monomer with two terminal olefin structures has great free radical polymerization potential, according to its physical and chemical properties and exploratory experimentation. Nature Publishing Group UK 2019-12-16 /pmc/articles/PMC6914792/ /pubmed/31844132 http://dx.doi.org/10.1038/s41598-019-55356-8 Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Gu, Yan
Hummel, Matthew
Muthukumarappan, Kasiviswanathan
Zhao, Zhendong
Gu, Zhengrong
Synthesis and Characterization of Allyl Terpene Maleate Monomer
title Synthesis and Characterization of Allyl Terpene Maleate Monomer
title_full Synthesis and Characterization of Allyl Terpene Maleate Monomer
title_fullStr Synthesis and Characterization of Allyl Terpene Maleate Monomer
title_full_unstemmed Synthesis and Characterization of Allyl Terpene Maleate Monomer
title_short Synthesis and Characterization of Allyl Terpene Maleate Monomer
title_sort synthesis and characterization of allyl terpene maleate monomer
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6914792/
https://www.ncbi.nlm.nih.gov/pubmed/31844132
http://dx.doi.org/10.1038/s41598-019-55356-8
work_keys_str_mv AT guyan synthesisandcharacterizationofallylterpenemaleatemonomer
AT hummelmatthew synthesisandcharacterizationofallylterpenemaleatemonomer
AT muthukumarappankasiviswanathan synthesisandcharacterizationofallylterpenemaleatemonomer
AT zhaozhendong synthesisandcharacterizationofallylterpenemaleatemonomer
AT guzhengrong synthesisandcharacterizationofallylterpenemaleatemonomer