Double Phosphinoboration of CO(2): A Facile Route to Diphospha‐Ureas

The reactions of CO(2) with a series of phosphinoboranes, including R(2)PBpin (R=Ph, tBu; pin=pinacol), R(2)PBMes(2) (R=Ph, tBu; Mes=2,4,6‐Me(3)‐C(6)H(2)), and R(2)PBcat (R=Ph, tBu, Mes; cat=catechol) are described. Although R(2)PBpin and R(2)PBMes(2) afford products of the form R(2)PCO(2)Bpin (R=Ph...

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Detalles Bibliográficos
Autores principales: LaFortune, James H. W., Qu, Zheng‐Wang, Bamford, Karlee L., Trofimova, Alina, Westcott, Stephen A., Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916295/
https://www.ncbi.nlm.nih.gov/pubmed/31355971
http://dx.doi.org/10.1002/chem.201903407

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