Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether

The unsaturated bicyclic acetal levoglucosenyl methyl ether was readily obtained from sustainable feedstock (cellulose) and polymerized by cationic ring‐opening polymerization to produce a semicrystalline thermoplastic unsaturated polyacetal with relatively high apparent molar mass (up to ca. 36 kg ...

Descripción completa

Detalles Bibliográficos
Autores principales: Debsharma, Tapas, Yagci, Yusuf, Schlaad, Helmut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916336/
https://www.ncbi.nlm.nih.gov/pubmed/31509324
http://dx.doi.org/10.1002/anie.201908458
_version_ 1783480215744282624
author Debsharma, Tapas
Yagci, Yusuf
Schlaad, Helmut
author_facet Debsharma, Tapas
Yagci, Yusuf
Schlaad, Helmut
author_sort Debsharma, Tapas
collection PubMed
description The unsaturated bicyclic acetal levoglucosenyl methyl ether was readily obtained from sustainable feedstock (cellulose) and polymerized by cationic ring‐opening polymerization to produce a semicrystalline thermoplastic unsaturated polyacetal with relatively high apparent molar mass (up to ca. 36 kg mol(−1)) and decent dispersity (ca. 1.4). The double bonds along the chain can undergo hydrogenation and thiol–ene reactions as well as crosslinking, thus making this polyacetal potentially interesting as a reactive functional material.
format Online
Article
Text
id pubmed-6916336
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-69163362019-12-17 Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether Debsharma, Tapas Yagci, Yusuf Schlaad, Helmut Angew Chem Int Ed Engl Communications The unsaturated bicyclic acetal levoglucosenyl methyl ether was readily obtained from sustainable feedstock (cellulose) and polymerized by cationic ring‐opening polymerization to produce a semicrystalline thermoplastic unsaturated polyacetal with relatively high apparent molar mass (up to ca. 36 kg mol(−1)) and decent dispersity (ca. 1.4). The double bonds along the chain can undergo hydrogenation and thiol–ene reactions as well as crosslinking, thus making this polyacetal potentially interesting as a reactive functional material. John Wiley and Sons Inc. 2019-10-25 2019-12-16 /pmc/articles/PMC6916336/ /pubmed/31509324 http://dx.doi.org/10.1002/anie.201908458 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Debsharma, Tapas
Yagci, Yusuf
Schlaad, Helmut
Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title_full Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title_fullStr Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title_full_unstemmed Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title_short Cellulose‐Derived Functional Polyacetal by Cationic Ring‐Opening Polymerization of Levoglucosenyl Methyl Ether
title_sort cellulose‐derived functional polyacetal by cationic ring‐opening polymerization of levoglucosenyl methyl ether
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916336/
https://www.ncbi.nlm.nih.gov/pubmed/31509324
http://dx.doi.org/10.1002/anie.201908458
work_keys_str_mv AT debsharmatapas cellulosederivedfunctionalpolyacetalbycationicringopeningpolymerizationoflevoglucosenylmethylether
AT yagciyusuf cellulosederivedfunctionalpolyacetalbycationicringopeningpolymerizationoflevoglucosenylmethylether
AT schlaadhelmut cellulosederivedfunctionalpolyacetalbycationicringopeningpolymerizationoflevoglucosenylmethylether

Ejemplares similares