Geometric E→Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti‐Metallometallation

An efficient geometrical E→Z isomerisation of alkenyl silanes is disclosed via selective energy transfer using an inexpensive organic sensitiser. Characterised by operational simplicity, short reaction times (2 h), and broad substrate tolerance, the reaction displays high selectivity for trisubstitu...

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Detalles Bibliográficos
Autores principales: Faßbender, Svenja I., Molloy, John J., Mück‐Lichtenfeld, Christian, Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916377/
https://www.ncbi.nlm.nih.gov/pubmed/31541612
http://dx.doi.org/10.1002/anie.201910169

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916377/
https://www.ncbi.nlm.nih.gov/pubmed/31541612
http://dx.doi.org/10.1002/anie.201910169

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