Recent Advances in the Chemistry of Heavier Group 14 Enolates

Recently heavier Group 14 enolates showed their importance and applicability in a broad range of chemical transformations. They were found to be key intermediates during the synthesis of photoinitiators, as well as during the formation of complex silicon frameworks. This Minireview presents general...

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Detalles Bibliográficos
Autor principal: Haas, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Minireviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916596/
https://www.ncbi.nlm.nih.gov/pubmed/31325194
http://dx.doi.org/10.1002/chem.201902307
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author Haas, Michael
author_facet Haas, Michael
author_sort Haas, Michael
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description Recently heavier Group 14 enolates showed their importance and applicability in a broad range of chemical transformations. They were found to be key intermediates during the synthesis of photoinitiators, as well as during the formation of complex silicon frameworks. This Minireview presents general strategies towards the synthesis of heavier Group 14 enolates (HG 14 enolates). Structural properties, as well as their spectroscopic behavior are outlined. This study may aid future development in this research area.
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spelling pubmed-69165962019-12-23 Recent Advances in the Chemistry of Heavier Group 14 Enolates Haas, Michael Chemistry Minireviews Recently heavier Group 14 enolates showed their importance and applicability in a broad range of chemical transformations. They were found to be key intermediates during the synthesis of photoinitiators, as well as during the formation of complex silicon frameworks. This Minireview presents general strategies towards the synthesis of heavier Group 14 enolates (HG 14 enolates). Structural properties, as well as their spectroscopic behavior are outlined. This study may aid future development in this research area. John Wiley and Sons Inc. 2019-09-19 2019-12-02 /pmc/articles/PMC6916596/ /pubmed/31325194 http://dx.doi.org/10.1002/chem.201902307 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Minireviews
Haas, Michael
Recent Advances in the Chemistry of Heavier Group 14 Enolates
title Recent Advances in the Chemistry of Heavier Group 14 Enolates
title_full Recent Advances in the Chemistry of Heavier Group 14 Enolates
title_fullStr Recent Advances in the Chemistry of Heavier Group 14 Enolates
title_full_unstemmed Recent Advances in the Chemistry of Heavier Group 14 Enolates
title_short Recent Advances in the Chemistry of Heavier Group 14 Enolates
title_sort recent advances in the chemistry of heavier group 14 enolates
topic Minireviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916596/
https://www.ncbi.nlm.nih.gov/pubmed/31325194
http://dx.doi.org/10.1002/chem.201902307
work_keys_str_mv AT haasmichael recentadvancesinthechemistryofheaviergroup14enolates

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