Binary Lead Fluoride Pb(3)F(8)

The binary lead fluoride Pb(3)F(8) was synthesized by the reaction of anhydrous HF with Pb(3)O(4) or by the reaction of BrF(3) with PbF(2). The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS (19)F NMR spectroscopy, as well as thermogravimetr...

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Detalles Bibliográficos
Autores principales: Deubner, H. Lars, Sachs, Malte, Bandemehr, Jascha, Ivlev, Sergei I., Karttunen, Antti J., Kachel, Stefan R., Klein, Benedikt P., Ruppenthal, Lukas, Schöniger, Maik, Krug, Claudio K., Herritsch, Jan, Gottfried, J. Michael, Aman, Jamal N. M., Schmedt auf der Günne, Jörn, Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916602/
https://www.ncbi.nlm.nih.gov/pubmed/31544988
http://dx.doi.org/10.1002/chem.201903954
Descripción
Sumario:The binary lead fluoride Pb(3)F(8) was synthesized by the reaction of anhydrous HF with Pb(3)O(4) or by the reaction of BrF(3) with PbF(2). The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS (19)F NMR spectroscopy, as well as thermogravimetric analysis, XP and near‐edge X‐ray absorption fine structure (NEXAFS) spectroscopy. Solid‐state quantum‐chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound.

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