Cargando…
Binary Lead Fluoride Pb(3)F(8)
The binary lead fluoride Pb(3)F(8) was synthesized by the reaction of anhydrous HF with Pb(3)O(4) or by the reaction of BrF(3) with PbF(2). The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS (19)F NMR spectroscopy, as well as thermogravimetr...
| Autores principales: | , , , , , , , , , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916602/ https://www.ncbi.nlm.nih.gov/pubmed/31544988 http://dx.doi.org/10.1002/chem.201903954 |
| _version_ | 1783480265847341056 |
|---|---|
| author | Deubner, H. Lars Sachs, Malte Bandemehr, Jascha Ivlev, Sergei I. Karttunen, Antti J. Kachel, Stefan R. Klein, Benedikt P. Ruppenthal, Lukas Schöniger, Maik Krug, Claudio K. Herritsch, Jan Gottfried, J. Michael Aman, Jamal N. M. Schmedt auf der Günne, Jörn Kraus, Florian |
| author_facet | Deubner, H. Lars Sachs, Malte Bandemehr, Jascha Ivlev, Sergei I. Karttunen, Antti J. Kachel, Stefan R. Klein, Benedikt P. Ruppenthal, Lukas Schöniger, Maik Krug, Claudio K. Herritsch, Jan Gottfried, J. Michael Aman, Jamal N. M. Schmedt auf der Günne, Jörn Kraus, Florian |
| author_sort | Deubner, H. Lars |
| collection | PubMed |
| description | The binary lead fluoride Pb(3)F(8) was synthesized by the reaction of anhydrous HF with Pb(3)O(4) or by the reaction of BrF(3) with PbF(2). The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS (19)F NMR spectroscopy, as well as thermogravimetric analysis, XP and near‐edge X‐ray absorption fine structure (NEXAFS) spectroscopy. Solid‐state quantum‐chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound. |
| format | Online Article Text |
| id | pubmed-6916602 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-69166022019-12-23 Binary Lead Fluoride Pb(3)F(8) Deubner, H. Lars Sachs, Malte Bandemehr, Jascha Ivlev, Sergei I. Karttunen, Antti J. Kachel, Stefan R. Klein, Benedikt P. Ruppenthal, Lukas Schöniger, Maik Krug, Claudio K. Herritsch, Jan Gottfried, J. Michael Aman, Jamal N. M. Schmedt auf der Günne, Jörn Kraus, Florian Chemistry Full Papers The binary lead fluoride Pb(3)F(8) was synthesized by the reaction of anhydrous HF with Pb(3)O(4) or by the reaction of BrF(3) with PbF(2). The compound was characterized by single‐crystal and powder X‐ray diffraction, IR, Raman, and solid‐state MAS (19)F NMR spectroscopy, as well as thermogravimetric analysis, XP and near‐edge X‐ray absorption fine structure (NEXAFS) spectroscopy. Solid‐state quantum‐chemical calculations are provided for the vibrational analyses and band assignments. The electronic band structure offers an inside view of the mixed valence compound. John Wiley and Sons Inc. 2019-11-04 2019-12-05 /pmc/articles/PMC6916602/ /pubmed/31544988 http://dx.doi.org/10.1002/chem.201903954 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Full Papers Deubner, H. Lars Sachs, Malte Bandemehr, Jascha Ivlev, Sergei I. Karttunen, Antti J. Kachel, Stefan R. Klein, Benedikt P. Ruppenthal, Lukas Schöniger, Maik Krug, Claudio K. Herritsch, Jan Gottfried, J. Michael Aman, Jamal N. M. Schmedt auf der Günne, Jörn Kraus, Florian Binary Lead Fluoride Pb(3)F(8) |
| title | Binary Lead Fluoride Pb(3)F(8)
|
| title_full | Binary Lead Fluoride Pb(3)F(8)
|
| title_fullStr | Binary Lead Fluoride Pb(3)F(8)
|
| title_full_unstemmed | Binary Lead Fluoride Pb(3)F(8)
|
| title_short | Binary Lead Fluoride Pb(3)F(8)
|
| title_sort | binary lead fluoride pb(3)f(8) |
| topic | Full Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916602/ https://www.ncbi.nlm.nih.gov/pubmed/31544988 http://dx.doi.org/10.1002/chem.201903954 |
| work_keys_str_mv | AT deubnerhlars binaryleadfluoridepb3f8 AT sachsmalte binaryleadfluoridepb3f8 AT bandemehrjascha binaryleadfluoridepb3f8 AT ivlevsergeii binaryleadfluoridepb3f8 AT karttunenanttij binaryleadfluoridepb3f8 AT kachelstefanr binaryleadfluoridepb3f8 AT kleinbenediktp binaryleadfluoridepb3f8 AT ruppenthallukas binaryleadfluoridepb3f8 AT schonigermaik binaryleadfluoridepb3f8 AT krugclaudiok binaryleadfluoridepb3f8 AT herritschjan binaryleadfluoridepb3f8 AT gottfriedjmichael binaryleadfluoridepb3f8 AT amanjamalnm binaryleadfluoridepb3f8 AT schmedtaufdergunnejorn binaryleadfluoridepb3f8 AT krausflorian binaryleadfluoridepb3f8 |