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Old Concepts, New Application – Additive‐Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex

An efficient additive‐free manganese‐catalyzed hydrogenation of nitriles to primary amines with molecular hydrogen is described. The pre‐catalyst, a well‐defined bench‐stable alkyl bisphosphine Mn(I) complex fac‐[Mn(dpre)(CO)(3)(CH(3))] (dpre=1,2‐bis(di‐n‐propylphosphino)ethane), undergoes CO migrat...

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Detalles Bibliográficos
Autores principales:	Weber, Stefan, Veiros, Luis F., Kirchner, Karl
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916632/ https://www.ncbi.nlm.nih.gov/pubmed/31875866 http://dx.doi.org/10.1002/adsc.201901040

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