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Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube
We report here the preparation and thermal, electrical and mechanical characterization of binary and ternary films based on l,d-poly(lactic acid) (l,d-PLA) and 4′-pentyl-4-biphenylcarbonitrile (5CB) and Single Walled Carbon Nanotubes (SWCN) with various weight ratio. The transitions for all investig...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918421/ https://www.ncbi.nlm.nih.gov/pubmed/31726773 http://dx.doi.org/10.3390/polym11111867 |
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author | Fryń, Patryk Bogdanowicz, Krzysztof Artur Krysiak, Piotr Marzec, Monika Iwan, Agnieszka Januszko, Adam |
author_facet | Fryń, Patryk Bogdanowicz, Krzysztof Artur Krysiak, Piotr Marzec, Monika Iwan, Agnieszka Januszko, Adam |
author_sort | Fryń, Patryk |
collection | PubMed |
description | We report here the preparation and thermal, electrical and mechanical characterization of binary and ternary films based on l,d-poly(lactic acid) (l,d-PLA) and 4′-pentyl-4-biphenylcarbonitrile (5CB) and Single Walled Carbon Nanotubes (SWCN) with various weight ratio. The transitions for all investigated hybrid compositions detected by differential scanning calorimetry method were shifted to lower temperatures with increasing the concentration of 5CB in the mixture with polymer. Frequency domain dielectric spectroscopy method and thermal imaging together with polarized optical microscope were used to study electric and structural properties of created hybrid compositions. The best electrical conductivity was observed for hybrid composite l,d-PLA:5CB:SWCN with ratio 10:1:0.5 w/w/w - resistance of 41.0 Ω and thermal response up to 160 °C without causing any damages. Films in crystal form are much more inflexible than in amorphous and can be explain by the cold crystallization occurs at heating while the materials changed their physical state. The value of ε′ increases with increasing the 5CB admixture. Moreover, the addition of 5CB to l,d-PLA resulted in increased flexibility of polymeric base films. The best material flexibility and short-term strength were obtained for l,d-PLA sample with 9% 5CB content. |
format | Online Article Text |
id | pubmed-6918421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-69184212019-12-24 Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube Fryń, Patryk Bogdanowicz, Krzysztof Artur Krysiak, Piotr Marzec, Monika Iwan, Agnieszka Januszko, Adam Polymers (Basel) Article We report here the preparation and thermal, electrical and mechanical characterization of binary and ternary films based on l,d-poly(lactic acid) (l,d-PLA) and 4′-pentyl-4-biphenylcarbonitrile (5CB) and Single Walled Carbon Nanotubes (SWCN) with various weight ratio. The transitions for all investigated hybrid compositions detected by differential scanning calorimetry method were shifted to lower temperatures with increasing the concentration of 5CB in the mixture with polymer. Frequency domain dielectric spectroscopy method and thermal imaging together with polarized optical microscope were used to study electric and structural properties of created hybrid compositions. The best electrical conductivity was observed for hybrid composite l,d-PLA:5CB:SWCN with ratio 10:1:0.5 w/w/w - resistance of 41.0 Ω and thermal response up to 160 °C without causing any damages. Films in crystal form are much more inflexible than in amorphous and can be explain by the cold crystallization occurs at heating while the materials changed their physical state. The value of ε′ increases with increasing the 5CB admixture. Moreover, the addition of 5CB to l,d-PLA resulted in increased flexibility of polymeric base films. The best material flexibility and short-term strength were obtained for l,d-PLA sample with 9% 5CB content. MDPI 2019-11-12 /pmc/articles/PMC6918421/ /pubmed/31726773 http://dx.doi.org/10.3390/polym11111867 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Fryń, Patryk Bogdanowicz, Krzysztof Artur Krysiak, Piotr Marzec, Monika Iwan, Agnieszka Januszko, Adam Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title | Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title_full | Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title_fullStr | Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title_full_unstemmed | Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title_short | Dielectric, Thermal and Mechanical Properties of l,d-Poly(Lactic Acid) Modified by 4′-Pentyl-4-Biphenylcarbonitrile and Single Walled Carbon Nanotube |
title_sort | dielectric, thermal and mechanical properties of l,d-poly(lactic acid) modified by 4′-pentyl-4-biphenylcarbonitrile and single walled carbon nanotube |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918421/ https://www.ncbi.nlm.nih.gov/pubmed/31726773 http://dx.doi.org/10.3390/polym11111867 |
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