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Nature of novel criticality in ternary transition-metal oxides

There are the chains of transition-metal cations alternating with the anions of oxygen in ternary transition-metal oxides. When a p-orbital of the oxygen connects the half-filled and empty d-orbitals of adjacent transition-metal cations, double-exchange ferromagnetism takes place. Although double ex...

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Autores principales: Abdulvagidov, Shapiullah B., Djabrailov, Shamil Z., Abdulvagidov, Belal Sh.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6920378/
https://www.ncbi.nlm.nih.gov/pubmed/31852927
http://dx.doi.org/10.1038/s41598-019-55594-w
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author Abdulvagidov, Shapiullah B.
Djabrailov, Shamil Z.
Abdulvagidov, Belal Sh.
author_facet Abdulvagidov, Shapiullah B.
Djabrailov, Shamil Z.
Abdulvagidov, Belal Sh.
author_sort Abdulvagidov, Shapiullah B.
collection PubMed
description There are the chains of transition-metal cations alternating with the anions of oxygen in ternary transition-metal oxides. When a p-orbital of the oxygen connects the half-filled and empty d-orbitals of adjacent transition-metal cations, double-exchange ferromagnetism takes place. Although double exchange has been well explored, the nature of novel criticality, induced by it, is yet not uncovered. We explored the magnetic-field scaling in the heat capacity of a Sm(0.55)Sr(0.45)MnO(3) manganite, one of the best ternary transition-metal oxides as it is completely ferromagnetic, and found novel criticality - unordinary critical exponents which are the consequence of coherence of Coulomb lattice distortion and ferromagnetism. The coherence is caused by the trinity of the mass, the charge and the spin of an electron. When the d and p orbitals overlaps, it quickly walks from one site to the another due its lightest mass. And due to its electric charge, it equalizes the valences of the transition-metal cations in the chains and so diminishes the Coulomb lattice distortion. At last, its spin forces magnetic moments of transition-metal cations to ferromagnetically arrange. The disappearance of Coulomb distortions widens the overlap and lowers the elastic lattice energy, so that not only the spin of an electron, but also its electric charge strengthens ferromagnetism. That nonlinear effect strengthens the critical behaviour and critical exponents come off any known universality classes. Thus, the symbiotic coherence of annihilating Coulomb distortions and arising ferromagnetism is a reason of the novel criticality.
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spelling pubmed-69203782019-12-20 Nature of novel criticality in ternary transition-metal oxides Abdulvagidov, Shapiullah B. Djabrailov, Shamil Z. Abdulvagidov, Belal Sh. Sci Rep Article There are the chains of transition-metal cations alternating with the anions of oxygen in ternary transition-metal oxides. When a p-orbital of the oxygen connects the half-filled and empty d-orbitals of adjacent transition-metal cations, double-exchange ferromagnetism takes place. Although double exchange has been well explored, the nature of novel criticality, induced by it, is yet not uncovered. We explored the magnetic-field scaling in the heat capacity of a Sm(0.55)Sr(0.45)MnO(3) manganite, one of the best ternary transition-metal oxides as it is completely ferromagnetic, and found novel criticality - unordinary critical exponents which are the consequence of coherence of Coulomb lattice distortion and ferromagnetism. The coherence is caused by the trinity of the mass, the charge and the spin of an electron. When the d and p orbitals overlaps, it quickly walks from one site to the another due its lightest mass. And due to its electric charge, it equalizes the valences of the transition-metal cations in the chains and so diminishes the Coulomb lattice distortion. At last, its spin forces magnetic moments of transition-metal cations to ferromagnetically arrange. The disappearance of Coulomb distortions widens the overlap and lowers the elastic lattice energy, so that not only the spin of an electron, but also its electric charge strengthens ferromagnetism. That nonlinear effect strengthens the critical behaviour and critical exponents come off any known universality classes. Thus, the symbiotic coherence of annihilating Coulomb distortions and arising ferromagnetism is a reason of the novel criticality. Nature Publishing Group UK 2019-12-18 /pmc/articles/PMC6920378/ /pubmed/31852927 http://dx.doi.org/10.1038/s41598-019-55594-w Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Abdulvagidov, Shapiullah B.
Djabrailov, Shamil Z.
Abdulvagidov, Belal Sh.
Nature of novel criticality in ternary transition-metal oxides
title Nature of novel criticality in ternary transition-metal oxides
title_full Nature of novel criticality in ternary transition-metal oxides
title_fullStr Nature of novel criticality in ternary transition-metal oxides
title_full_unstemmed Nature of novel criticality in ternary transition-metal oxides
title_short Nature of novel criticality in ternary transition-metal oxides
title_sort nature of novel criticality in ternary transition-metal oxides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6920378/
https://www.ncbi.nlm.nih.gov/pubmed/31852927
http://dx.doi.org/10.1038/s41598-019-55594-w
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