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Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
[Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6921262/ https://www.ncbi.nlm.nih.gov/pubmed/31867486 http://dx.doi.org/10.1021/acsomega.9b02105 |
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author | Omambala, Joshua R. McIntyre, Ernest C. Gallo, August A. |
author_facet | Omambala, Joshua R. McIntyre, Ernest C. Gallo, August A. |
author_sort | Omambala, Joshua R. |
collection | PubMed |
description | [Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown. The hydrolyzation route has been used in the synthesis, the microstructure has been displayed using scanning electron microscopy, the yield has been ascertained, and the compound has been characterized. The rheological properties are demonstrated on the ER fluid through steady flow and oscillatory tests to investigate the effects of change in concentration on the functional group attached to the inorganic silicon–oxygen core structure of the POSS compound. The electrorheological efficiency was analyzed, and dielectric characterization was done. The flow curve was described by the Herschel–Bulkley model, and yield stress values were derived from the model. The octa-cyanoPOSS/PDMS electrorheological fluid has been shown to have ER activity. |
format | Online Article Text |
id | pubmed-6921262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical
Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-69212622019-12-20 Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure Omambala, Joshua R. McIntyre, Ernest C. Gallo, August A. ACS Omega [Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown. The hydrolyzation route has been used in the synthesis, the microstructure has been displayed using scanning electron microscopy, the yield has been ascertained, and the compound has been characterized. The rheological properties are demonstrated on the ER fluid through steady flow and oscillatory tests to investigate the effects of change in concentration on the functional group attached to the inorganic silicon–oxygen core structure of the POSS compound. The electrorheological efficiency was analyzed, and dielectric characterization was done. The flow curve was described by the Herschel–Bulkley model, and yield stress values were derived from the model. The octa-cyanoPOSS/PDMS electrorheological fluid has been shown to have ER activity. American Chemical Society 2019-12-02 /pmc/articles/PMC6921262/ /pubmed/31867486 http://dx.doi.org/10.1021/acsomega.9b02105 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Omambala, Joshua R. McIntyre, Ernest C. Gallo, August A. Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure |
title | Electrorheological
Effects of Synthesized Octa-cyanopropylsilsesquioxane
Cage Structure |
title_full | Electrorheological
Effects of Synthesized Octa-cyanopropylsilsesquioxane
Cage Structure |
title_fullStr | Electrorheological
Effects of Synthesized Octa-cyanopropylsilsesquioxane
Cage Structure |
title_full_unstemmed | Electrorheological
Effects of Synthesized Octa-cyanopropylsilsesquioxane
Cage Structure |
title_short | Electrorheological
Effects of Synthesized Octa-cyanopropylsilsesquioxane
Cage Structure |
title_sort | electrorheological
effects of synthesized octa-cyanopropylsilsesquioxane
cage structure |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6921262/ https://www.ncbi.nlm.nih.gov/pubmed/31867486 http://dx.doi.org/10.1021/acsomega.9b02105 |
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