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Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure

[Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown...

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Autores principales: Omambala, Joshua R., McIntyre, Ernest C., Gallo, August A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6921262/
https://www.ncbi.nlm.nih.gov/pubmed/31867486
http://dx.doi.org/10.1021/acsomega.9b02105
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author Omambala, Joshua R.
McIntyre, Ernest C.
Gallo, August A.
author_facet Omambala, Joshua R.
McIntyre, Ernest C.
Gallo, August A.
author_sort Omambala, Joshua R.
collection PubMed
description [Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown. The hydrolyzation route has been used in the synthesis, the microstructure has been displayed using scanning electron microscopy, the yield has been ascertained, and the compound has been characterized. The rheological properties are demonstrated on the ER fluid through steady flow and oscillatory tests to investigate the effects of change in concentration on the functional group attached to the inorganic silicon–oxygen core structure of the POSS compound. The electrorheological efficiency was analyzed, and dielectric characterization was done. The flow curve was described by the Herschel–Bulkley model, and yield stress values were derived from the model. The octa-cyanoPOSS/PDMS electrorheological fluid has been shown to have ER activity.
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spelling pubmed-69212622019-12-20 Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure Omambala, Joshua R. McIntyre, Ernest C. Gallo, August A. ACS Omega [Image: see text] This article introduces a new electrorheological (ER) fluid. A molecular cage structure for electrorheological applications has been synthesized, and the ER behavior of the octa-functionalized polyhedral oligomeric silsesquioxane (POSS) variant in silicone oil (PDMS) has been shown. The hydrolyzation route has been used in the synthesis, the microstructure has been displayed using scanning electron microscopy, the yield has been ascertained, and the compound has been characterized. The rheological properties are demonstrated on the ER fluid through steady flow and oscillatory tests to investigate the effects of change in concentration on the functional group attached to the inorganic silicon–oxygen core structure of the POSS compound. The electrorheological efficiency was analyzed, and dielectric characterization was done. The flow curve was described by the Herschel–Bulkley model, and yield stress values were derived from the model. The octa-cyanoPOSS/PDMS electrorheological fluid has been shown to have ER activity. American Chemical Society 2019-12-02 /pmc/articles/PMC6921262/ /pubmed/31867486 http://dx.doi.org/10.1021/acsomega.9b02105 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Omambala, Joshua R.
McIntyre, Ernest C.
Gallo, August A.
Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title_full Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title_fullStr Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title_full_unstemmed Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title_short Electrorheological Effects of Synthesized Octa-cyanopropylsilsesquioxane Cage Structure
title_sort electrorheological effects of synthesized octa-cyanopropylsilsesquioxane cage structure
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6921262/
https://www.ncbi.nlm.nih.gov/pubmed/31867486
http://dx.doi.org/10.1021/acsomega.9b02105
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