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Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism
The CeCu oxide catalyst CC450 was prepared by citric acid complex method and the catalytic wet peroxide oxidation (CWPO) reaction system was established with bisphenol A (BPA) as the target pollutant. By means of characterization, this research investigated the phase structure, surface morphology, r...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6926835/ https://www.ncbi.nlm.nih.gov/pubmed/31771209 http://dx.doi.org/10.3390/ijerph16234675 |
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author | Jiao, Zhaojie Chen, Ligong Zhou, Guilin Gong, Haifeng Zhang, Xianming Liu, Yunqi Gao, Xu |
author_facet | Jiao, Zhaojie Chen, Ligong Zhou, Guilin Gong, Haifeng Zhang, Xianming Liu, Yunqi Gao, Xu |
author_sort | Jiao, Zhaojie |
collection | PubMed |
description | The CeCu oxide catalyst CC450 was prepared by citric acid complex method and the catalytic wet peroxide oxidation (CWPO) reaction system was established with bisphenol A (BPA) as the target pollutant. By means of characterization, this research investigated the phase structure, surface morphology, reducibility, surface element composition, and valence of the catalyst before and after reuse. The effects of catalyst dosage and pH on the removal efficiency of BPA were also investigated. Five reuse experiments were carried out to investigate the reusability of the catalyst. In addition, this research delved into the changes of pH value, hydroxyl radical concentration, and ultraviolet-visible spectra of BPA in CWPO reaction system. The possible intermediate products were analyzed by gas chromatography-mass spectrometry (GC-MS). The catalytic mechanism and degradation pathway were also discussed. The results showed that after reaction of 65 min, the removal of BPA and total organic carbon (TOC) could reach 87.6% and 77.9%, respectively. The catalyst showed strong pH adaptability and had high removal efficiency of BPA in the range of pH 1.6–7.9. After five reuses, the removal of BPA remained above 86.7%, with the structure of the catalyst remaining stable to a large extent. With the reaction proceeding, the pH value of the reaction solution increased, the concentration of OH radicals decreased, and the ultraviolet-visible spectrum of BPA shifted to the short wavelength direction, that is, the blue shift direction. The catalysts degraded BPA rapidly in CWPO reaction system and the C–C bond or O–H bond in BPA could be destroyed in a very short time. Also, there may have been two main degradation paths of phenol and ketone. |
format | Online Article Text |
id | pubmed-6926835 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-69268352019-12-23 Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism Jiao, Zhaojie Chen, Ligong Zhou, Guilin Gong, Haifeng Zhang, Xianming Liu, Yunqi Gao, Xu Int J Environ Res Public Health Article The CeCu oxide catalyst CC450 was prepared by citric acid complex method and the catalytic wet peroxide oxidation (CWPO) reaction system was established with bisphenol A (BPA) as the target pollutant. By means of characterization, this research investigated the phase structure, surface morphology, reducibility, surface element composition, and valence of the catalyst before and after reuse. The effects of catalyst dosage and pH on the removal efficiency of BPA were also investigated. Five reuse experiments were carried out to investigate the reusability of the catalyst. In addition, this research delved into the changes of pH value, hydroxyl radical concentration, and ultraviolet-visible spectra of BPA in CWPO reaction system. The possible intermediate products were analyzed by gas chromatography-mass spectrometry (GC-MS). The catalytic mechanism and degradation pathway were also discussed. The results showed that after reaction of 65 min, the removal of BPA and total organic carbon (TOC) could reach 87.6% and 77.9%, respectively. The catalyst showed strong pH adaptability and had high removal efficiency of BPA in the range of pH 1.6–7.9. After five reuses, the removal of BPA remained above 86.7%, with the structure of the catalyst remaining stable to a large extent. With the reaction proceeding, the pH value of the reaction solution increased, the concentration of OH radicals decreased, and the ultraviolet-visible spectrum of BPA shifted to the short wavelength direction, that is, the blue shift direction. The catalysts degraded BPA rapidly in CWPO reaction system and the C–C bond or O–H bond in BPA could be destroyed in a very short time. Also, there may have been two main degradation paths of phenol and ketone. MDPI 2019-11-23 2019-12 /pmc/articles/PMC6926835/ /pubmed/31771209 http://dx.doi.org/10.3390/ijerph16234675 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Jiao, Zhaojie Chen, Ligong Zhou, Guilin Gong, Haifeng Zhang, Xianming Liu, Yunqi Gao, Xu Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title | Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title_full | Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title_fullStr | Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title_full_unstemmed | Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title_short | Degradation of Bisphenol A by CeCu Oxide Catalyst in Catalytic Wet Peroxide Oxidation: Efficiency, Stability, and Mechanism |
title_sort | degradation of bisphenol a by cecu oxide catalyst in catalytic wet peroxide oxidation: efficiency, stability, and mechanism |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6926835/ https://www.ncbi.nlm.nih.gov/pubmed/31771209 http://dx.doi.org/10.3390/ijerph16234675 |
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