Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence

[Image: see text] A mixed alkali-metal nonlinear optical (NLO) dihydro-cyanurate crystal Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O has been synthesized via the hydrothermal method. Its calculated birefringence is about 0.368, which is very large, its ultraviolet (UV) cutoff edge is down to 230 nm, and the...

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Detalles Bibliográficos
Autores principales: Aibibula, Mukeremu, Wang, Li, Huang, Shuzhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6933788/
https://www.ncbi.nlm.nih.gov/pubmed/31891102
http://dx.doi.org/10.1021/acsomega.9b03490
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author Aibibula, Mukeremu
Wang, Li
Huang, Shuzhao
author_facet Aibibula, Mukeremu
Wang, Li
Huang, Shuzhao
author_sort Aibibula, Mukeremu
collection PubMed
description [Image: see text] A mixed alkali-metal nonlinear optical (NLO) dihydro-cyanurate crystal Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O has been synthesized via the hydrothermal method. Its calculated birefringence is about 0.368, which is very large, its ultraviolet (UV) cutoff edge is down to 230 nm, and the powder second harmonic generation (SHG) intensity is about 0.2 × KDP. In addition, a first-principles investigation of the electronic properties on Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O was carried out. The calculated band gap and SHG coefficient values agree well with the experimental ones. These results suggest that it could be applied as a UV birefringent material.
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spelling pubmed-69337882019-12-30 Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence Aibibula, Mukeremu Wang, Li Huang, Shuzhao ACS Omega [Image: see text] A mixed alkali-metal nonlinear optical (NLO) dihydro-cyanurate crystal Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O has been synthesized via the hydrothermal method. Its calculated birefringence is about 0.368, which is very large, its ultraviolet (UV) cutoff edge is down to 230 nm, and the powder second harmonic generation (SHG) intensity is about 0.2 × KDP. In addition, a first-principles investigation of the electronic properties on Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O was carried out. The calculated band gap and SHG coefficient values agree well with the experimental ones. These results suggest that it could be applied as a UV birefringent material. American Chemical Society 2019-12-13 /pmc/articles/PMC6933788/ /pubmed/31891102 http://dx.doi.org/10.1021/acsomega.9b03490 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Aibibula, Mukeremu
Wang, Li
Huang, Shuzhao
Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title_full Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title_fullStr Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title_full_unstemmed Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title_short Rb(3)Na(H(2)C(3)N(3)O(3))(4)·3H(2)O with Large Birefringence
title_sort rb(3)na(h(2)c(3)n(3)o(3))(4)·3h(2)o with large birefringence
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6933788/
https://www.ncbi.nlm.nih.gov/pubmed/31891102
http://dx.doi.org/10.1021/acsomega.9b03490
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