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Octametallic Cluster of Cp*Ir(glycinato) Cations

[Image: see text] Removal of chloride from Cp*Ir(glycinato)Cl in noncoordinating solvents with Ag[PF(6)] or Tl[PF(6)] leads to the formation of a closed octametallic loop of cations. The same loop also sequesters a number of PF(6)(–) counter anions. This is in contrast with reports that piano-stool...

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Detalles Bibliográficos
Autores principales: Morris, David M., Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6933806/
https://www.ncbi.nlm.nih.gov/pubmed/31891094
http://dx.doi.org/10.1021/acsomega.9b03267