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Unusual Epimerization in Styryllactones: Synthesis of (−)-5-Hydroxygoniothalamin, (−)-5-Acetylgoniothalamin, and O-TBS-Goniopypyrone

[Image: see text] (−)-5-Hydroxygoniothalamin, (−)-5-acetylgoniothalamin, and (+)-5-hydroxygoniothalamin, isolated from the Goniothalamus genus, are synthesized from triacetyl-O-d-glucal by employing the Ferrier reaction, Mitsunobu reaction, and Jones oxidation as key steps. The synthetic procedure a...

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Detalles Bibliográficos
Autores principales: Kotammagari, Tharun K., Paul, Sayantan, Bhattacharya, Asish K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6941370/
https://www.ncbi.nlm.nih.gov/pubmed/31909338
http://dx.doi.org/10.1021/acsomega.9b03263