Inkjet-Printed Imbedded Graphene Nanoplatelet/Zinc Oxide Bulk Heterojunctions Nanocomposite Films for Ultraviolet Photodetection

[Image: see text] A ZnO sol–gel precursor (ZnOPr) and graphene nanoplatelets (GnPs) are mixed into a composite ink for inkjet printing photodetectors with bulk heterojunctions of ZnO/GnP on a heated SiO(2)/Si substrate. Heating of the SiO(2)/Si wafers at ∼50 °C was found optimal to prevent segregated droplets on the hydrophobic surface of the SiO(2)/Si substrate during printing. After printing the ZnO/GnP channels, thermal annealing at 350 °C for 2 h was performed for crystallization of ZnO and formation of the ZnO/GnP heterojunctions. The GnP concentration was varied from 0, 5, 20, and 30 mM to evaluate optimal formation of the ZnO/GnP bulk heterojunction nanocomposites based on ultraviolet photoresponse performance. The best performance was observed at the 20 mM GnP concentration with the photoresponsivity reaching 2.2 A/W at an incident ultraviolet power of 2.2 μW and a 5 V bias. This photoresponsivity is an order of magnitude better than the previously reported counterparts, including 0.13 mA/W for dropcasted ZnO-graphite composites and much higher than 0.5 A/W for aerosol printed ZnO. The improved performance is attributed to the ZnO/GnP bulk heterojunctions with improved interfaces that enable efficient exciton dissociation and the charge transport. The developed inkjet printing of sol–gel composite inks approach can be scalable and low cost for practical applications.