Construction of trisubstituted chromone skeletons carrying electron-withdrawing groups via PhIO-mediated dehydrogenation and its application to the synthesis of frutinone A

The construction of the biologically interesting chromone skeleton was realized by PhIO-mediated dehydrogenation of chromanones under mild conditions. Interestingly, this method also found application in the synthesis of the naturally occurring frutinone A.

Detalles Bibliográficos
Autores principales: Li, Qiao, Zhuang, Chen, Wang, Donghua, Zhang, Wei, Jia, Rongxuan, Sun, Fengxia, Zhang, Yilin, Du, Yunfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6941426/
https://www.ncbi.nlm.nih.gov/pubmed/31921367
http://dx.doi.org/10.3762/bjoc.15.291
Descripción
Sumario:The construction of the biologically interesting chromone skeleton was realized by PhIO-mediated dehydrogenation of chromanones under mild conditions. Interestingly, this method also found application in the synthesis of the naturally occurring frutinone A.

Ejemplares similares