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Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp(3))-H Bond Allylation
The alkoxyl radical is an essential reactive intermediate in mechanistic studies and organic synthesis with hydrogen atom transfer (HAT) reactivity. However, compared with intramolecular 1,5-HAT or intermolecular HAT of alkoxyl radicals, the intramolecular 1,2-HAT reactivity has been limited to theo...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6941871/ https://www.ncbi.nlm.nih.gov/pubmed/31884167 http://dx.doi.org/10.1016/j.isci.2019.100755 |