Unexpected Rearrangement of N-Allyl-2-phenyl-4,5-Dihydrooxazole-4-Carboxamides to Construct Aza-Quaternary Carbon Centers

The unexpected rearrangement of N-allyl-2-phenyl-4,5-dihydrooxazole-4-carboxamides in the presence of LiHMDS has been found. The key features are: (1) the net reaction consisted of 1,3-migration of the N-allyl group, (2) the rearrangement produced a congested aza-quaternary carbon center, (3) both c...

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Detalles Bibliográficos
Autores principales: Choi, Goyeong, Jo, Seoyoung, Mun, Juyeon, Jeong, Yonguk, Kim, Seok-Ho, Jung, Jong-Wha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6943665/
https://www.ncbi.nlm.nih.gov/pubmed/31817984
http://dx.doi.org/10.3390/molecules24244495

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6943665/
https://www.ncbi.nlm.nih.gov/pubmed/31817984
http://dx.doi.org/10.3390/molecules24244495

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