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Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation

Efficient one-pot synthesis of new series of furylpyrazolino[60]fullerene derivatives was prepared by [3 + 2] cycloaddition reaction mediated with (diacetoxyiodo)benzene (PhI(OAc)(2)) as an oxidant in o-dichlorobenzene (ODCB) under microwave irradiation. Different techniques have been used to confir...

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Autores principales: Al-Matar, Hamad M., BinSabt, Mohammad H., Shalaby, Mona A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6943683/
https://www.ncbi.nlm.nih.gov/pubmed/31817136
http://dx.doi.org/10.3390/molecules24244435
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author Al-Matar, Hamad M.
BinSabt, Mohammad H.
Shalaby, Mona A.
author_facet Al-Matar, Hamad M.
BinSabt, Mohammad H.
Shalaby, Mona A.
author_sort Al-Matar, Hamad M.
collection PubMed
description Efficient one-pot synthesis of new series of furylpyrazolino[60]fullerene derivatives was prepared by [3 + 2] cycloaddition reaction mediated with (diacetoxyiodo)benzene (PhI(OAc)(2)) as an oxidant in o-dichlorobenzene (ODCB) under microwave irradiation. Different techniques have been used to confirm the structural identity including FT-IR, fast atom bombardment (FAB)-mass, NMR, and single-crystal X-ray diffraction, in addition to investigating the photophysical properties and the electrochemical properties for the new compounds using UV-Vis spectra, fluorescence spectra, cyclic voltammetry, and square wave voltammetry. Three of these pyrazolino[60]fullerene compounds showed better electron affinity than the parent C(60) in the ground state.
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spelling pubmed-69436832020-01-10 Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation Al-Matar, Hamad M. BinSabt, Mohammad H. Shalaby, Mona A. Molecules Article Efficient one-pot synthesis of new series of furylpyrazolino[60]fullerene derivatives was prepared by [3 + 2] cycloaddition reaction mediated with (diacetoxyiodo)benzene (PhI(OAc)(2)) as an oxidant in o-dichlorobenzene (ODCB) under microwave irradiation. Different techniques have been used to confirm the structural identity including FT-IR, fast atom bombardment (FAB)-mass, NMR, and single-crystal X-ray diffraction, in addition to investigating the photophysical properties and the electrochemical properties for the new compounds using UV-Vis spectra, fluorescence spectra, cyclic voltammetry, and square wave voltammetry. Three of these pyrazolino[60]fullerene compounds showed better electron affinity than the parent C(60) in the ground state. MDPI 2019-12-04 /pmc/articles/PMC6943683/ /pubmed/31817136 http://dx.doi.org/10.3390/molecules24244435 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Al-Matar, Hamad M.
BinSabt, Mohammad H.
Shalaby, Mona A.
Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title_full Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title_fullStr Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title_full_unstemmed Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title_short Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
title_sort synthesis and electrochemistry of new furylpyrazolino[60]fullerene derivatives by efficient microwave radiation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6943683/
https://www.ncbi.nlm.nih.gov/pubmed/31817136
http://dx.doi.org/10.3390/molecules24244435
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