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Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether
The molecule of the title compound, C(28)H(22)N(4)O(9), exhibits crystallographically imposed twofold rotational symmetry, with a dihedral angle of 66.0 (2)° between the planes of the two central benzene rings bounded to the central oxygen atom. The dihedral angle between the planes of the central...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6944087/ https://www.ncbi.nlm.nih.gov/pubmed/31921459 http://dx.doi.org/10.1107/S2056989019016852 |
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| author | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Mohiuddin, Md. Sarker, Md. Sohug Salim, Mohammad Alam, Md. Mahbubul |
| author_facet | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Mohiuddin, Md. Sarker, Md. Sohug Salim, Mohammad Alam, Md. Mahbubul |
| author_sort | Arafath, Md. Azharul |
| collection | PubMed |
| description | The molecule of the title compound, C(28)H(22)N(4)O(9), exhibits crystallographically imposed twofold rotational symmetry, with a dihedral angle of 66.0 (2)° between the planes of the two central benzene rings bounded to the central oxygen atom. The dihedral angle between the planes of the central benzene ring and the terminal phenol ring is 4.9 (2)°. Each half of the molecule exhibits an imine E configuration. An intramolecular O—H⋯N hydrogen bond is present. In the crystal, the molecules are linked into layers parallel to the ab plane via C—H⋯O hydrogen bonds. The crystal studied was refined as a two-component pseudomerohedral twin. |
| format | Online Article Text |
| id | pubmed-6944087 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-69440872020-01-09 Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Mohiuddin, Md. Sarker, Md. Sohug Salim, Mohammad Alam, Md. Mahbubul Acta Crystallogr E Crystallogr Commun Research Communications The molecule of the title compound, C(28)H(22)N(4)O(9), exhibits crystallographically imposed twofold rotational symmetry, with a dihedral angle of 66.0 (2)° between the planes of the two central benzene rings bounded to the central oxygen atom. The dihedral angle between the planes of the central benzene ring and the terminal phenol ring is 4.9 (2)°. Each half of the molecule exhibits an imine E configuration. An intramolecular O—H⋯N hydrogen bond is present. In the crystal, the molecules are linked into layers parallel to the ab plane via C—H⋯O hydrogen bonds. The crystal studied was refined as a two-component pseudomerohedral twin. International Union of Crystallography 2020-01-01 /pmc/articles/PMC6944087/ /pubmed/31921459 http://dx.doi.org/10.1107/S2056989019016852 Text en © Arafath et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Mohiuddin, Md. Sarker, Md. Sohug Salim, Mohammad Alam, Md. Mahbubul Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title | Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title_full | Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title_fullStr | Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title_full_unstemmed | Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title_short | Bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| title_sort | bis{4-[(2-hydroxy-5-methoxy-3-nitrobenzylidene)amino]phenyl} ether |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6944087/ https://www.ncbi.nlm.nih.gov/pubmed/31921459 http://dx.doi.org/10.1107/S2056989019016852 |
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