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Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose
Interface optimization in preparing natural fiber based biocomposite becomes a key factor that determines overall properties, especially mechanical performance. The solution for upgrading interfacial adhesion stemmed from polar fiber and nonpolar polymer remains unclear. Here, a kind of pulp fiber/a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960529/ https://www.ncbi.nlm.nih.gov/pubmed/31835578 http://dx.doi.org/10.3390/polym11122048 |
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author | Zhu, Qinrui Li, Dagang |
author_facet | Zhu, Qinrui Li, Dagang |
author_sort | Zhu, Qinrui |
collection | PubMed |
description | Interface optimization in preparing natural fiber based biocomposite becomes a key factor that determines overall properties, especially mechanical performance. The solution for upgrading interfacial adhesion stemmed from polar fiber and nonpolar polymer remains unclear. Here, a kind of pulp fiber/acrylonitrile-butadiene-styrene (ABS) composite with content ratio of 1:1 was fabricated by functionalizing the cellulose fiber to coordinate interaction between fiber and ABS. With addition of 5 wt % polyacrylamide (PAM) there existed an interlinked three-element structure in composite. Three types of treatment to cellulose fiber, including alkali immersion, pivaloyl chloride grafting for 10 h and 20 h were conducted. Pulp fiber that was treated with alkali for one hour, followed by pivaloyl chloride reaction for ten hours, proved to be effective for interfacial adhesion. X-ray Photoelectron Spectroscopy (XPS) analysis reveals 21.9% of carbonyl and 12.1% of ester function in this fiber, which corresponds to oxidation and grafting. For its composite SEM picture displays that most of cellulose fiber are rooted in ABS and evident traces of tearing or fracture can be observed after tension test. DMA test indicates that this modified pulp fiber/ABS composite exhibits great compatibility, because of combined loss modulus peak ranging from 80 °C to 100 °C. Moreover, the well miscible composite has a tensile strength of 58.1 MPa and elastic modulus of 2515 MPa, increasing by nearly 50% and 60% from those of pure ABS, respectively. |
format | Online Article Text |
id | pubmed-6960529 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-69605292020-01-23 Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose Zhu, Qinrui Li, Dagang Polymers (Basel) Article Interface optimization in preparing natural fiber based biocomposite becomes a key factor that determines overall properties, especially mechanical performance. The solution for upgrading interfacial adhesion stemmed from polar fiber and nonpolar polymer remains unclear. Here, a kind of pulp fiber/acrylonitrile-butadiene-styrene (ABS) composite with content ratio of 1:1 was fabricated by functionalizing the cellulose fiber to coordinate interaction between fiber and ABS. With addition of 5 wt % polyacrylamide (PAM) there existed an interlinked three-element structure in composite. Three types of treatment to cellulose fiber, including alkali immersion, pivaloyl chloride grafting for 10 h and 20 h were conducted. Pulp fiber that was treated with alkali for one hour, followed by pivaloyl chloride reaction for ten hours, proved to be effective for interfacial adhesion. X-ray Photoelectron Spectroscopy (XPS) analysis reveals 21.9% of carbonyl and 12.1% of ester function in this fiber, which corresponds to oxidation and grafting. For its composite SEM picture displays that most of cellulose fiber are rooted in ABS and evident traces of tearing or fracture can be observed after tension test. DMA test indicates that this modified pulp fiber/ABS composite exhibits great compatibility, because of combined loss modulus peak ranging from 80 °C to 100 °C. Moreover, the well miscible composite has a tensile strength of 58.1 MPa and elastic modulus of 2515 MPa, increasing by nearly 50% and 60% from those of pure ABS, respectively. MDPI 2019-12-10 /pmc/articles/PMC6960529/ /pubmed/31835578 http://dx.doi.org/10.3390/polym11122048 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zhu, Qinrui Li, Dagang Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title | Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title_full | Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title_fullStr | Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title_full_unstemmed | Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title_short | Interface Reinforcement of Pulp Fiber Based ABS Composite with Hydrogen Bonding Initiated Interlinked Structure via Alkaline Oxidation and tert-Butyl Grafting on Cellulose |
title_sort | interface reinforcement of pulp fiber based abs composite with hydrogen bonding initiated interlinked structure via alkaline oxidation and tert-butyl grafting on cellulose |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960529/ https://www.ncbi.nlm.nih.gov/pubmed/31835578 http://dx.doi.org/10.3390/polym11122048 |
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