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Microfibrillated Cellulose Suspension and Its Electrorheology

Microfibrillated cellulose (MFC) particles were synthesized by a low-pressure alkaline delignification process, and their shape and chemical structure were investigated by SEM and Fourier transformation infrared spectroscopy, respectively. As a novel electrorheological (ER) material, the MFC particu...

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Autores principales: Choi, Kisuk, Nam, Jae Do, Kwon, Seung Hyuk, Choi, Hyoung Jin, Islam, Md Sakinul, Kao, Nhol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960754/
https://www.ncbi.nlm.nih.gov/pubmed/31861094
http://dx.doi.org/10.3390/polym11122119
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author Choi, Kisuk
Nam, Jae Do
Kwon, Seung Hyuk
Choi, Hyoung Jin
Islam, Md Sakinul
Kao, Nhol
author_facet Choi, Kisuk
Nam, Jae Do
Kwon, Seung Hyuk
Choi, Hyoung Jin
Islam, Md Sakinul
Kao, Nhol
author_sort Choi, Kisuk
collection PubMed
description Microfibrillated cellulose (MFC) particles were synthesized by a low-pressure alkaline delignification process, and their shape and chemical structure were investigated by SEM and Fourier transformation infrared spectroscopy, respectively. As a novel electrorheological (ER) material, the MFC particulate sample was suspended in insulating oil to fabricate an ER fluid. Its rheological properties—steady shear stress, shear viscosity, yield stress, and dynamic moduli—under electric field strength were characterized by a rotational rheometer. The MFC-based ER fluid demonstrated typical ER characteristics, in which the shear stresses followed the Cho–Choi–Jhon model well under electric field strength. In addition, the solid-like behavior of the ER fluid was investigated with the Schwarzl equation. The elevated value of both dynamic and elastic yield stresses at applied electric field strengths was well described using a power law model (~E(1.5)). The reversible and quick response of the ER fluid was also illustrated through the on–off test.
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spelling pubmed-69607542020-01-23 Microfibrillated Cellulose Suspension and Its Electrorheology Choi, Kisuk Nam, Jae Do Kwon, Seung Hyuk Choi, Hyoung Jin Islam, Md Sakinul Kao, Nhol Polymers (Basel) Article Microfibrillated cellulose (MFC) particles were synthesized by a low-pressure alkaline delignification process, and their shape and chemical structure were investigated by SEM and Fourier transformation infrared spectroscopy, respectively. As a novel electrorheological (ER) material, the MFC particulate sample was suspended in insulating oil to fabricate an ER fluid. Its rheological properties—steady shear stress, shear viscosity, yield stress, and dynamic moduli—under electric field strength were characterized by a rotational rheometer. The MFC-based ER fluid demonstrated typical ER characteristics, in which the shear stresses followed the Cho–Choi–Jhon model well under electric field strength. In addition, the solid-like behavior of the ER fluid was investigated with the Schwarzl equation. The elevated value of both dynamic and elastic yield stresses at applied electric field strengths was well described using a power law model (~E(1.5)). The reversible and quick response of the ER fluid was also illustrated through the on–off test. MDPI 2019-12-17 /pmc/articles/PMC6960754/ /pubmed/31861094 http://dx.doi.org/10.3390/polym11122119 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Choi, Kisuk
Nam, Jae Do
Kwon, Seung Hyuk
Choi, Hyoung Jin
Islam, Md Sakinul
Kao, Nhol
Microfibrillated Cellulose Suspension and Its Electrorheology
title Microfibrillated Cellulose Suspension and Its Electrorheology
title_full Microfibrillated Cellulose Suspension and Its Electrorheology
title_fullStr Microfibrillated Cellulose Suspension and Its Electrorheology
title_full_unstemmed Microfibrillated Cellulose Suspension and Its Electrorheology
title_short Microfibrillated Cellulose Suspension and Its Electrorheology
title_sort microfibrillated cellulose suspension and its electrorheology
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960754/
https://www.ncbi.nlm.nih.gov/pubmed/31861094
http://dx.doi.org/10.3390/polym11122119
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