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Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction

The accumulation of carbon dioxide (CO(2)) pollutants in the atmosphere begets global warming, forcing us to face tangible catastrophes worldwide. Environmental affability, affordability, and efficient CO(2) metamorphotic capacity are critical factors for photocatalysts; metal-organic frameworks (MO...

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Autores principales: Kidanemariam, Alemayehu, Lee, Jiwon, Park, Juhyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960843/
https://www.ncbi.nlm.nih.gov/pubmed/31847223
http://dx.doi.org/10.3390/polym11122090
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author Kidanemariam, Alemayehu
Lee, Jiwon
Park, Juhyun
author_facet Kidanemariam, Alemayehu
Lee, Jiwon
Park, Juhyun
author_sort Kidanemariam, Alemayehu
collection PubMed
description The accumulation of carbon dioxide (CO(2)) pollutants in the atmosphere begets global warming, forcing us to face tangible catastrophes worldwide. Environmental affability, affordability, and efficient CO(2) metamorphotic capacity are critical factors for photocatalysts; metal-organic frameworks (MOFs) are one of the best candidates. MOFs, as hybrid organic ligand and inorganic nodal metal with tailorable morphological texture and adaptable electronic structure, are contemporary artificial photocatalysts. The semiconducting nature and porous topology of MOFs, respectively, assists with photogenerated multi-exciton injection and adsorption of substrate proximate to void cavities, thereby converting CO(2). The vitality of the employment of MOFs in CO(2) photolytic reaction has emerged from the fact that they are not only an inherently eco-friendly weapon for pollutant extermination, but also a potential tool for alleviating foreseeable fuel crises. The excellent synergistic interaction between the central metal and organic linker allows decisive implementation for the design, integration, and application of the catalytic bundle. In this review, we presented recent MOF headway focusing on reports of the last three years, exhaustively categorized based on central metal-type, and novel discussion, from material preparation to photocatalytic, simulated performance recordings of respective as-synthesized materials. The selective CO(2) reduction capacities into syngas or formate of standalone or composite MOFs with definite photocatalytic reaction conditions was considered and compared.
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spelling pubmed-69608432020-01-24 Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction Kidanemariam, Alemayehu Lee, Jiwon Park, Juhyun Polymers (Basel) Review The accumulation of carbon dioxide (CO(2)) pollutants in the atmosphere begets global warming, forcing us to face tangible catastrophes worldwide. Environmental affability, affordability, and efficient CO(2) metamorphotic capacity are critical factors for photocatalysts; metal-organic frameworks (MOFs) are one of the best candidates. MOFs, as hybrid organic ligand and inorganic nodal metal with tailorable morphological texture and adaptable electronic structure, are contemporary artificial photocatalysts. The semiconducting nature and porous topology of MOFs, respectively, assists with photogenerated multi-exciton injection and adsorption of substrate proximate to void cavities, thereby converting CO(2). The vitality of the employment of MOFs in CO(2) photolytic reaction has emerged from the fact that they are not only an inherently eco-friendly weapon for pollutant extermination, but also a potential tool for alleviating foreseeable fuel crises. The excellent synergistic interaction between the central metal and organic linker allows decisive implementation for the design, integration, and application of the catalytic bundle. In this review, we presented recent MOF headway focusing on reports of the last three years, exhaustively categorized based on central metal-type, and novel discussion, from material preparation to photocatalytic, simulated performance recordings of respective as-synthesized materials. The selective CO(2) reduction capacities into syngas or formate of standalone or composite MOFs with definite photocatalytic reaction conditions was considered and compared. MDPI 2019-12-13 /pmc/articles/PMC6960843/ /pubmed/31847223 http://dx.doi.org/10.3390/polym11122090 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Kidanemariam, Alemayehu
Lee, Jiwon
Park, Juhyun
Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title_full Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title_fullStr Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title_full_unstemmed Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title_short Recent Innovation of Metal-Organic Frameworks for Carbon Dioxide Photocatalytic Reduction
title_sort recent innovation of metal-organic frameworks for carbon dioxide photocatalytic reduction
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960843/
https://www.ncbi.nlm.nih.gov/pubmed/31847223
http://dx.doi.org/10.3390/polym11122090
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