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Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism

Polymer dielectrics subjected to intense radiation fluxes exhibit a radiation-induced conductivity (RIC). Polyimide is a good dielectric with excellent mechanical and thermal properties featuring high radiation resistance currently widely used in the spacecraft industry. Its RIC has been extensively...

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Autores principales: Tyutnev, Andrey, Saenko, Vladimir, Zhadov, Aleksei, Pozhidaev, Evgenii
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960874/
https://www.ncbi.nlm.nih.gov/pubmed/31835797
http://dx.doi.org/10.3390/polym11122061
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author Tyutnev, Andrey
Saenko, Vladimir
Zhadov, Aleksei
Pozhidaev, Evgenii
author_facet Tyutnev, Andrey
Saenko, Vladimir
Zhadov, Aleksei
Pozhidaev, Evgenii
author_sort Tyutnev, Andrey
collection PubMed
description Polymer dielectrics subjected to intense radiation fluxes exhibit a radiation-induced conductivity (RIC). Polyimide is a good dielectric with excellent mechanical and thermal properties featuring high radiation resistance currently widely used in the spacecraft industry. Its RIC has been extensively studied in several laboratories. The purpose of the present study is to make a direct measurement of the RIC for both pulsed and continuous irradiation using a current sensing technique, which is contrary to the indirect method employing a surface-potential decay technique that is now preferred by spacecraft charging engineers. Our experiments are done in a small-signal regime excluding any recombination and dose effects. In combination with existing computer codes, we managed to develop further the conventional multiple trapping formalism and the RIC theory based on it. The main idea is to supplement an exponential trap distribution responsible for a dominant dispersive carrier transport in polymers with a small concentration of inherent deep traps which may or may not have an energy distribution. In line with this reasoning, we propose a tentative set of RIC model parameters for polyimide that accounts for the observed experimental data. The findings and their implications are discussed in a broad context of previous studies.
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spelling pubmed-69608742020-01-24 Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism Tyutnev, Andrey Saenko, Vladimir Zhadov, Aleksei Pozhidaev, Evgenii Polymers (Basel) Article Polymer dielectrics subjected to intense radiation fluxes exhibit a radiation-induced conductivity (RIC). Polyimide is a good dielectric with excellent mechanical and thermal properties featuring high radiation resistance currently widely used in the spacecraft industry. Its RIC has been extensively studied in several laboratories. The purpose of the present study is to make a direct measurement of the RIC for both pulsed and continuous irradiation using a current sensing technique, which is contrary to the indirect method employing a surface-potential decay technique that is now preferred by spacecraft charging engineers. Our experiments are done in a small-signal regime excluding any recombination and dose effects. In combination with existing computer codes, we managed to develop further the conventional multiple trapping formalism and the RIC theory based on it. The main idea is to supplement an exponential trap distribution responsible for a dominant dispersive carrier transport in polymers with a small concentration of inherent deep traps which may or may not have an energy distribution. In line with this reasoning, we propose a tentative set of RIC model parameters for polyimide that accounts for the observed experimental data. The findings and their implications are discussed in a broad context of previous studies. MDPI 2019-12-11 /pmc/articles/PMC6960874/ /pubmed/31835797 http://dx.doi.org/10.3390/polym11122061 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tyutnev, Andrey
Saenko, Vladimir
Zhadov, Aleksei
Pozhidaev, Evgenii
Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title_full Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title_fullStr Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title_full_unstemmed Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title_short Time-Resolved Radiation-Induced Conductivity of Polyimide and Its Description Using the Multiple Trapping Formalism
title_sort time-resolved radiation-induced conductivity of polyimide and its description using the multiple trapping formalism
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6960874/
https://www.ncbi.nlm.nih.gov/pubmed/31835797
http://dx.doi.org/10.3390/polym11122061
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