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Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst

[Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction,...

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Autores principales: Naikwade, Altafhusen G., Jagadale, Megha B., Kale, Dolly P., Gophane, Anna D., Garadkar, Kalyanrao M., Rashinkar, Gajanan S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963935/
https://www.ncbi.nlm.nih.gov/pubmed/31956760
http://dx.doi.org/10.1021/acsomega.9b02040
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author Naikwade, Altafhusen G.
Jagadale, Megha B.
Kale, Dolly P.
Gophane, Anna D.
Garadkar, Kalyanrao M.
Rashinkar, Gajanan S.
author_facet Naikwade, Altafhusen G.
Jagadale, Megha B.
Kale, Dolly P.
Gophane, Anna D.
Garadkar, Kalyanrao M.
Rashinkar, Gajanan S.
author_sort Naikwade, Altafhusen G.
collection PubMed
description [Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, and vibrating sample magnetometer analysis. The optical properties of the photocatalyst were probed by photoluminescence and UV–vis diffuse reflectance spectroscopy. The discharge of undesirable dye effluents from textile industrial plants in the environment is the major concern of environmental pollution and toxicity. In this context, we employed the as-prepared SILP photocatalyst for degradation of methyl orange (MO) under UV light (365 nm) irradiation, and subsequently, recycling studies were performed. The histological alteration in gills of the fish is employed as a tool for monitoring toxins in the environment. In view of this, the histo-toxicological assessment on freshwater fish Tilapia mossambica gills asserted the damage of secondary gill lamellae due to MO. Conversely, structural modifications in the gill architecture were not observed by virtue of photodegraded products confirming that the degraded product is nontoxic in nature. Additionally, the normal behavior of fishes on exposure to photodegraded products reveals that research findings are beneficial for the aquatic ecosystem.
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spelling pubmed-69639352020-01-17 Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst Naikwade, Altafhusen G. Jagadale, Megha B. Kale, Dolly P. Gophane, Anna D. Garadkar, Kalyanrao M. Rashinkar, Gajanan S. ACS Omega [Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, and vibrating sample magnetometer analysis. The optical properties of the photocatalyst were probed by photoluminescence and UV–vis diffuse reflectance spectroscopy. The discharge of undesirable dye effluents from textile industrial plants in the environment is the major concern of environmental pollution and toxicity. In this context, we employed the as-prepared SILP photocatalyst for degradation of methyl orange (MO) under UV light (365 nm) irradiation, and subsequently, recycling studies were performed. The histological alteration in gills of the fish is employed as a tool for monitoring toxins in the environment. In view of this, the histo-toxicological assessment on freshwater fish Tilapia mossambica gills asserted the damage of secondary gill lamellae due to MO. Conversely, structural modifications in the gill architecture were not observed by virtue of photodegraded products confirming that the degraded product is nontoxic in nature. Additionally, the normal behavior of fishes on exposure to photodegraded products reveals that research findings are beneficial for the aquatic ecosystem. American Chemical Society 2020-01-03 /pmc/articles/PMC6963935/ /pubmed/31956760 http://dx.doi.org/10.1021/acsomega.9b02040 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Naikwade, Altafhusen G.
Jagadale, Megha B.
Kale, Dolly P.
Gophane, Anna D.
Garadkar, Kalyanrao M.
Rashinkar, Gajanan S.
Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title_full Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title_fullStr Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title_full_unstemmed Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title_short Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
title_sort photocatalytic degradation of methyl orange by magnetically retrievable supported ionic liquid phase photocatalyst
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963935/
https://www.ncbi.nlm.nih.gov/pubmed/31956760
http://dx.doi.org/10.1021/acsomega.9b02040
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