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Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst
[Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction,...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963935/ https://www.ncbi.nlm.nih.gov/pubmed/31956760 http://dx.doi.org/10.1021/acsomega.9b02040 |
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author | Naikwade, Altafhusen G. Jagadale, Megha B. Kale, Dolly P. Gophane, Anna D. Garadkar, Kalyanrao M. Rashinkar, Gajanan S. |
author_facet | Naikwade, Altafhusen G. Jagadale, Megha B. Kale, Dolly P. Gophane, Anna D. Garadkar, Kalyanrao M. Rashinkar, Gajanan S. |
author_sort | Naikwade, Altafhusen G. |
collection | PubMed |
description | [Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, and vibrating sample magnetometer analysis. The optical properties of the photocatalyst were probed by photoluminescence and UV–vis diffuse reflectance spectroscopy. The discharge of undesirable dye effluents from textile industrial plants in the environment is the major concern of environmental pollution and toxicity. In this context, we employed the as-prepared SILP photocatalyst for degradation of methyl orange (MO) under UV light (365 nm) irradiation, and subsequently, recycling studies were performed. The histological alteration in gills of the fish is employed as a tool for monitoring toxins in the environment. In view of this, the histo-toxicological assessment on freshwater fish Tilapia mossambica gills asserted the damage of secondary gill lamellae due to MO. Conversely, structural modifications in the gill architecture were not observed by virtue of photodegraded products confirming that the degraded product is nontoxic in nature. Additionally, the normal behavior of fishes on exposure to photodegraded products reveals that research findings are beneficial for the aquatic ecosystem. |
format | Online Article Text |
id | pubmed-6963935 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-69639352020-01-17 Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst Naikwade, Altafhusen G. Jagadale, Megha B. Kale, Dolly P. Gophane, Anna D. Garadkar, Kalyanrao M. Rashinkar, Gajanan S. ACS Omega [Image: see text] A magnetically retrievable ferrocene appended supported ionic liquid phase (SILP) photocatalyst containing a molybdate anion has been synthesized and characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray diffraction, energy dispersive spectroscopy, and vibrating sample magnetometer analysis. The optical properties of the photocatalyst were probed by photoluminescence and UV–vis diffuse reflectance spectroscopy. The discharge of undesirable dye effluents from textile industrial plants in the environment is the major concern of environmental pollution and toxicity. In this context, we employed the as-prepared SILP photocatalyst for degradation of methyl orange (MO) under UV light (365 nm) irradiation, and subsequently, recycling studies were performed. The histological alteration in gills of the fish is employed as a tool for monitoring toxins in the environment. In view of this, the histo-toxicological assessment on freshwater fish Tilapia mossambica gills asserted the damage of secondary gill lamellae due to MO. Conversely, structural modifications in the gill architecture were not observed by virtue of photodegraded products confirming that the degraded product is nontoxic in nature. Additionally, the normal behavior of fishes on exposure to photodegraded products reveals that research findings are beneficial for the aquatic ecosystem. American Chemical Society 2020-01-03 /pmc/articles/PMC6963935/ /pubmed/31956760 http://dx.doi.org/10.1021/acsomega.9b02040 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Naikwade, Altafhusen G. Jagadale, Megha B. Kale, Dolly P. Gophane, Anna D. Garadkar, Kalyanrao M. Rashinkar, Gajanan S. Photocatalytic Degradation of Methyl Orange by Magnetically Retrievable Supported Ionic Liquid Phase Photocatalyst |
title | Photocatalytic Degradation of Methyl Orange by Magnetically
Retrievable Supported Ionic Liquid Phase Photocatalyst |
title_full | Photocatalytic Degradation of Methyl Orange by Magnetically
Retrievable Supported Ionic Liquid Phase Photocatalyst |
title_fullStr | Photocatalytic Degradation of Methyl Orange by Magnetically
Retrievable Supported Ionic Liquid Phase Photocatalyst |
title_full_unstemmed | Photocatalytic Degradation of Methyl Orange by Magnetically
Retrievable Supported Ionic Liquid Phase Photocatalyst |
title_short | Photocatalytic Degradation of Methyl Orange by Magnetically
Retrievable Supported Ionic Liquid Phase Photocatalyst |
title_sort | photocatalytic degradation of methyl orange by magnetically
retrievable supported ionic liquid phase photocatalyst |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963935/ https://www.ncbi.nlm.nih.gov/pubmed/31956760 http://dx.doi.org/10.1021/acsomega.9b02040 |
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