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Efficient and New Production Methods of Chemicals and Liquid Fuels by Carbon Monoxide Hydrogenation

[Image: see text] Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the n...

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Detalles Bibliográficos
Autores principales: Du, Ce, Lu, Peng, Tsubaki, Noritatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6963990/
https://www.ncbi.nlm.nih.gov/pubmed/31956750
http://dx.doi.org/10.1021/acsomega.9b03577
Descripción
Sumario:[Image: see text] Carbon monoxide (CO) hydrogenation is an important step for efficient utilization of carbon resources in C1 (one carbon) chemistry. Over recent years, this direction has been a hot research area in academia and industry and has also been one of the most challenging routes for the nonoil carbon resources utilization process. A large number of novel reaction routes and catalysts have been studied and reported. Efficient activation and directional conversion of CO are key aspects in the process of CO utilization. Furthermore, effectively activating C–O and C–C bond formation as well as controlling carbon chain growth is the current technical bottleneck of CO hydrogenation. This mini-review introduces the latest research progress for different catalyst systems and processes in CO hydrogenation and analyzes the factors that control the performance of catalysts in different reaction systems. Here, much focus is put on the synthesis of long-chain hydrocarbons, light olefins, C(2+) oxygenates, and aromatics, essentially in comparison with the previous reports. Finally, the present challenges and future research directions have been discussed.