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Experimental Evidence for Algebraic Double-Layer Forces

[Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping a...

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Detalles Bibliográficos
Autores principales: Stojimirović, Biljana, Vis, Mark, Tuinier, Remco, Philipse, Albert P., Trefalt, Gregor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968886/
https://www.ncbi.nlm.nih.gov/pubmed/31834805
http://dx.doi.org/10.1021/acs.langmuir.9b03077
Descripción
Sumario:[Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping as well as counterion-only regimes, albeit the evidence is less clear for the former regime. In both of these cases, the disjoining pressure profile assumes an inverse square distance dependence. At small separation distances, another algebraic regime is recovered. In this regime, the pressure decays as the inverse of separation distance.