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Experimental Evidence for Algebraic Double-Layer Forces
[Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968886/ https://www.ncbi.nlm.nih.gov/pubmed/31834805 http://dx.doi.org/10.1021/acs.langmuir.9b03077 |
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author | Stojimirović, Biljana Vis, Mark Tuinier, Remco Philipse, Albert P. Trefalt, Gregor |
author_facet | Stojimirović, Biljana Vis, Mark Tuinier, Remco Philipse, Albert P. Trefalt, Gregor |
author_sort | Stojimirović, Biljana |
collection | PubMed |
description | [Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping as well as counterion-only regimes, albeit the evidence is less clear for the former regime. In both of these cases, the disjoining pressure profile assumes an inverse square distance dependence. At small separation distances, another algebraic regime is recovered. In this regime, the pressure decays as the inverse of separation distance. |
format | Online Article Text |
id | pubmed-6968886 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American
Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-69688862020-01-21 Experimental Evidence for Algebraic Double-Layer Forces Stojimirović, Biljana Vis, Mark Tuinier, Remco Philipse, Albert P. Trefalt, Gregor Langmuir [Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping as well as counterion-only regimes, albeit the evidence is less clear for the former regime. In both of these cases, the disjoining pressure profile assumes an inverse square distance dependence. At small separation distances, another algebraic regime is recovered. In this regime, the pressure decays as the inverse of separation distance. American Chemical Society 2019-12-13 2020-01-14 /pmc/articles/PMC6968886/ /pubmed/31834805 http://dx.doi.org/10.1021/acs.langmuir.9b03077 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Stojimirović, Biljana Vis, Mark Tuinier, Remco Philipse, Albert P. Trefalt, Gregor Experimental Evidence for Algebraic Double-Layer Forces |
title | Experimental Evidence for Algebraic Double-Layer Forces |
title_full | Experimental Evidence for Algebraic Double-Layer Forces |
title_fullStr | Experimental Evidence for Algebraic Double-Layer Forces |
title_full_unstemmed | Experimental Evidence for Algebraic Double-Layer Forces |
title_short | Experimental Evidence for Algebraic Double-Layer Forces |
title_sort | experimental evidence for algebraic double-layer forces |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968886/ https://www.ncbi.nlm.nih.gov/pubmed/31834805 http://dx.doi.org/10.1021/acs.langmuir.9b03077 |
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