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Experimental Evidence for Algebraic Double-Layer Forces

[Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping a...

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Autores principales: Stojimirović, Biljana, Vis, Mark, Tuinier, Remco, Philipse, Albert P., Trefalt, Gregor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968886/
https://www.ncbi.nlm.nih.gov/pubmed/31834805
http://dx.doi.org/10.1021/acs.langmuir.9b03077
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author Stojimirović, Biljana
Vis, Mark
Tuinier, Remco
Philipse, Albert P.
Trefalt, Gregor
author_facet Stojimirović, Biljana
Vis, Mark
Tuinier, Remco
Philipse, Albert P.
Trefalt, Gregor
author_sort Stojimirović, Biljana
collection PubMed
description [Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping as well as counterion-only regimes, albeit the evidence is less clear for the former regime. In both of these cases, the disjoining pressure profile assumes an inverse square distance dependence. At small separation distances, another algebraic regime is recovered. In this regime, the pressure decays as the inverse of separation distance.
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spelling pubmed-69688862020-01-21 Experimental Evidence for Algebraic Double-Layer Forces Stojimirović, Biljana Vis, Mark Tuinier, Remco Philipse, Albert P. Trefalt, Gregor Langmuir [Image: see text] According to conventional wisdom, electric double-layer forces normally decay exponentially with separation distance. Here, we present experimental evidence of algebraically decaying double-layer interactions. We show that algebraic interactions arise in both strongly overlapping as well as counterion-only regimes, albeit the evidence is less clear for the former regime. In both of these cases, the disjoining pressure profile assumes an inverse square distance dependence. At small separation distances, another algebraic regime is recovered. In this regime, the pressure decays as the inverse of separation distance. American Chemical Society 2019-12-13 2020-01-14 /pmc/articles/PMC6968886/ /pubmed/31834805 http://dx.doi.org/10.1021/acs.langmuir.9b03077 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Stojimirović, Biljana
Vis, Mark
Tuinier, Remco
Philipse, Albert P.
Trefalt, Gregor
Experimental Evidence for Algebraic Double-Layer Forces
title Experimental Evidence for Algebraic Double-Layer Forces
title_full Experimental Evidence for Algebraic Double-Layer Forces
title_fullStr Experimental Evidence for Algebraic Double-Layer Forces
title_full_unstemmed Experimental Evidence for Algebraic Double-Layer Forces
title_short Experimental Evidence for Algebraic Double-Layer Forces
title_sort experimental evidence for algebraic double-layer forces
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968886/
https://www.ncbi.nlm.nih.gov/pubmed/31834805
http://dx.doi.org/10.1021/acs.langmuir.9b03077
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