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Single Electron Transfer to Diazomethane–Borane Adducts Prompts C−H Bond Activations
While (Ph(2)CN(2))B(C(6)F(5))(3) is unstable, single electron transfer from Cp*(2)Co affords the isolation of stable products [Cp*(2)Co][Ph(2)CNNHB(C(6)F(5))(3)] 1 and [Cp*Co(C(5)Me(4)CH(2)B(C(6)F(5))(3))] 2. The analogous combination of Ph(2)CN(2) and BPh(3) showed no evidence of adduct formation a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972512/ https://www.ncbi.nlm.nih.gov/pubmed/31589360 http://dx.doi.org/10.1002/anie.201912338 |