Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)

Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P)(2) m] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and qua...

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Detalles Bibliográficos
Autores principales: Balmer, Markus, Franzke, Yannick J., Weigend, Florian, von Hänisch, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972534/
https://www.ncbi.nlm.nih.gov/pubmed/31702848
http://dx.doi.org/10.1002/chem.201905061
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author Balmer, Markus
Franzke, Yannick J.
Weigend, Florian
von Hänisch, Carsten
author_facet Balmer, Markus
Franzke, Yannick J.
Weigend, Florian
von Hänisch, Carsten
author_sort Balmer, Markus
collection PubMed
description Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P)(2) m] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and quantum‐chemical methods. Furthermore, the monosubstituted compounds [(SIDippP)MX](2) (M=Sn, X=Cl; M=Pb, X=Br) are presented, which show dimeric structures instead of multiple bonding interaction.
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spelling pubmed-69725342020-01-27 Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb) Balmer, Markus Franzke, Yannick J. Weigend, Florian von Hänisch, Carsten Chemistry Communications Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P)(2) m] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and quantum‐chemical methods. Furthermore, the monosubstituted compounds [(SIDippP)MX](2) (M=Sn, X=Cl; M=Pb, X=Br) are presented, which show dimeric structures instead of multiple bonding interaction. John Wiley and Sons Inc. 2019-12-03 2020-01-02 /pmc/articles/PMC6972534/ /pubmed/31702848 http://dx.doi.org/10.1002/chem.201905061 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Balmer, Markus
Franzke, Yannick J.
Weigend, Florian
von Hänisch, Carsten
Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title_full Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title_fullStr Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title_full_unstemmed Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title_short Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
title_sort low‐valent group 14 phosphinidenide complexes [({sidipp}p)(2)m] exhibit p–m pπ–pπ interaction (m=ge, sn, pb)
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972534/
https://www.ncbi.nlm.nih.gov/pubmed/31702848
http://dx.doi.org/10.1002/chem.201905061
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