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Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)(2)M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp}P)(2) m] exhibiting P–M pπ–pπ interactions (SIDipp=1,3‐bis(2,6‐diisopropylphenyl)‐imidazolidin‐2‐ylidene, M=Ge, Sn, Pb), is presented. These compounds were investigated by means of structural, spectroscopic, and qua...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972534/ https://www.ncbi.nlm.nih.gov/pubmed/31702848 http://dx.doi.org/10.1002/chem.201905061 |