Mild, Selective Ru‐Catalyzed Deuteration Using D(2)O as a Deuterium Source

A method for the selective deuteration of polyfunctional organic molecules using catalytic amounts of [RuCl(2)(PPh(3))(3)] and D(2)O as a deuterium source is presented. Through variation of additives like CuI, KOH, and various amounts of zinc powder, orthogonal chemoselectivities in the deuteration...

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Detalles Bibliográficos
Autores principales: Eisele, Pascal, Ullwer, Franziska, Scholz, Sven, Plietker, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972544/
https://www.ncbi.nlm.nih.gov/pubmed/31680359
http://dx.doi.org/10.1002/chem.201904927

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972544/
https://www.ncbi.nlm.nih.gov/pubmed/31680359
http://dx.doi.org/10.1002/chem.201904927

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