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Mild, Selective Ru‐Catalyzed Deuteration Using D(2)O as a Deuterium Source
A method for the selective deuteration of polyfunctional organic molecules using catalytic amounts of [RuCl(2)(PPh(3))(3)] and D(2)O as a deuterium source is presented. Through variation of additives like CuI, KOH, and various amounts of zinc powder, orthogonal chemoselectivities in the deuteration...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972544/ https://www.ncbi.nlm.nih.gov/pubmed/31680359 http://dx.doi.org/10.1002/chem.201904927 |