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Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions
Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar*GeH(2)](−) reacts with hafnocene dichloride under formation of the substitution product [Cp(2)Hf(GeH(2)Ar*)(2)]. Reaction of the organodihydridostannate...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972602/ https://www.ncbi.nlm.nih.gov/pubmed/31535431 http://dx.doi.org/10.1002/chem.201903652 |
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author | Maudrich, Jakob‐Jonathan Widemann, Max Diab, Fatima Kern, Ralf H. Sirsch, Peter Sindlinger, Christian P. Schubert, Hartmut Wesemann, Lars |
author_facet | Maudrich, Jakob‐Jonathan Widemann, Max Diab, Fatima Kern, Ralf H. Sirsch, Peter Sindlinger, Christian P. Schubert, Hartmut Wesemann, Lars |
author_sort | Maudrich, Jakob‐Jonathan |
collection | PubMed |
description | Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar*GeH(2)](−) reacts with hafnocene dichloride under formation of the substitution product [Cp(2)Hf(GeH(2)Ar*)(2)]. Reaction of the organodihydridostannate with metallocene dichlorides affords the reduction products [Cp(2)M(SnHAr*)(2)] (M=Ti, Zr, Hf). Abstraction of a hydride substituent from the titanium bis(hydridoorganostannylene) complex results in formation of cation [Cp(2)M(SnAr*)(SnHAr*)](+) exhibiting a short Ti–Sn interaction. (Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐triisopropylphenyl). |
format | Online Article Text |
id | pubmed-6972602 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-69726022020-01-27 Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions Maudrich, Jakob‐Jonathan Widemann, Max Diab, Fatima Kern, Ralf H. Sirsch, Peter Sindlinger, Christian P. Schubert, Hartmut Wesemann, Lars Chemistry Full Papers Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar*GeH(2)](−) reacts with hafnocene dichloride under formation of the substitution product [Cp(2)Hf(GeH(2)Ar*)(2)]. Reaction of the organodihydridostannate with metallocene dichlorides affords the reduction products [Cp(2)M(SnHAr*)(2)] (M=Ti, Zr, Hf). Abstraction of a hydride substituent from the titanium bis(hydridoorganostannylene) complex results in formation of cation [Cp(2)M(SnAr*)(SnHAr*)](+) exhibiting a short Ti–Sn interaction. (Ar*=2,6‐Trip(2)C(6)H(3), Trip=2,4,6‐triisopropylphenyl). John Wiley and Sons Inc. 2019-11-13 2019-12-13 /pmc/articles/PMC6972602/ /pubmed/31535431 http://dx.doi.org/10.1002/chem.201903652 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Full Papers Maudrich, Jakob‐Jonathan Widemann, Max Diab, Fatima Kern, Ralf H. Sirsch, Peter Sindlinger, Christian P. Schubert, Hartmut Wesemann, Lars Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title | Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title_full | Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title_fullStr | Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title_full_unstemmed | Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title_short | Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions |
title_sort | hydridoorganostannylene coordination: group 4 metallocene dichloride reduction in reaction with organodihydridostannate anions |
topic | Full Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972602/ https://www.ncbi.nlm.nih.gov/pubmed/31535431 http://dx.doi.org/10.1002/chem.201903652 |
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