Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs

By applying caged thymidine residues, DNA duplexes were created in which Hg(II)‐mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal‐mediated base pairs was ac...

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Detalles Bibliográficos
Autores principales: Naskar, Shuvankar, Müller, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972992/
https://www.ncbi.nlm.nih.gov/pubmed/31682036
http://dx.doi.org/10.1002/chem.201903789
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author Naskar, Shuvankar
Müller, Jens
author_facet Naskar, Shuvankar
Müller, Jens
author_sort Naskar, Shuvankar
collection PubMed
description By applying caged thymidine residues, DNA duplexes were created in which Hg(II)‐mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal‐mediated base pairs was achieved.
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spelling pubmed-69729922020-01-27 Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs Naskar, Shuvankar Müller, Jens Chemistry Communications By applying caged thymidine residues, DNA duplexes were created in which Hg(II)‐mediated base pair formation can be triggered by irradiation with light. When a bidentate ligand was used as the complementary nucleobase, an unprecedented stepwise formation of different metal‐mediated base pairs was achieved. John Wiley and Sons Inc. 2019-11-19 2019-12-18 /pmc/articles/PMC6972992/ /pubmed/31682036 http://dx.doi.org/10.1002/chem.201903789 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Naskar, Shuvankar
Müller, Jens
Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title_full Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title_fullStr Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title_full_unstemmed Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title_short Light‐Induced Formation of Thymine‐Containing Mercury(II)‐Mediated Base Pairs
title_sort light‐induced formation of thymine‐containing mercury(ii)‐mediated base pairs
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972992/
https://www.ncbi.nlm.nih.gov/pubmed/31682036
http://dx.doi.org/10.1002/chem.201903789
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