Cargando…

Dehydrogenative Anodic C−C Coupling of Phenols Bearing Electron‐Withdrawing Groups

We herein present a metal‐free, electrosynthetic method that enables the direct dehydrogenative coupling reactions of phenols carrying electron‐withdrawing groups for the first time. The reactions are easy to conduct and scalable, as they are carried out in undivided cells and obviate the necessity...

Descripción completa

Detalles Bibliográficos
Autores principales:	Röckl, Johannes L., Schollmeyer, Dieter, Franke, Robert, Waldvogel, Siegfried R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973026/ https://www.ncbi.nlm.nih.gov/pubmed/31498544 http://dx.doi.org/10.1002/anie.201910077

Ejemplares similares

Electrochemical synthesis of N,N′-disubstituted indazolin-3-ones via an intramolecular anodic dehydrogenative N–N coupling reaction
por: Bieniek, Jessica C., et al.
Publicado: (2022)

Electrochemical Synthesis of Carbazoles by Dehydrogenative Coupling Reaction
por: Kehl, Anton, et al.
Publicado: (2020)

Electrochemical C−H Functionalization of (Hetero)Arenes—Optimized by DoE
por: Dörr, Maurice, et al.
Publicado: (2020)

Electrochemical Synthesis of Fluorinated Orthoesters from 1,3‐Benzodioxoles
por: Röckl, Johannes L., et al.
Publicado: (2019)

Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N‐Cyanosulfilimines
por: Klein, Martin, et al.
Publicado: (2021)

Direct electrochemical generation of organic carbonates by dehydrogenative coupling
por: Gieshoff, Tile, et al.
Publicado: (2018)

About the selectivity and reactivity of active nickel electrodes in C–C coupling reactions
por: Beil, Sebastian B., et al.
Publicado: (2020)

Developments in the Dehydrogenative Electrochemical Synthesis of 3,3′,5,5′‐Tetramethyl‐2,2′‐biphenol
por: Gleede, Barbara, et al.
Publicado: (2021)

Photocatalytic dehydrogenative C-C coupling of acetonitrile to succinonitrile
por: Zhou, Xian, et al.
Publicado: (2022)

Mechanism of the Dehydrogenative Phenothiazination of Phenols
por: Goswami, Monalisa, et al.
Publicado: (2018)

Cross-dehydrogenative coupling for the intermolecular C–O bond formation
por: Krylov, Igor B, et al.
Publicado: (2015)

Crystal structure of ethyl 2-(diethoxyphosphoryl)-2-(2,3,4-trimethoxyphenyl)acetate
por: Schubert, Moritz, et al.
Publicado: (2014)

Application of Chan-Lam cross coupling for the synthesis of N-heterocyclic carbene precursors bearing strong electron donating or withdrawing groups
por: Huang, Liliang, et al.
Publicado: (2015)

Solvent‐Dependent Facile Synthesis of Diaryl Selenides and Biphenols Employing Selenium Dioxide
por: Quell, Thomas, et al.
Publicado: (2015)

Dehydrogenative C–H Phenochalcogenazination
por: Cremer, Christopher, et al.
Publicado: (2021)

Dehydrogenative Imination of Low-Valent Sulfur Compounds—Fast and Scalable Synthesis of Sulfilimines, Sulfinamidines, and Sulfinimidate Esters
por: Klein, Martin, et al.
Publicado: (2023)

Iron catalyzed C–C dehydrogenative coupling reaction: synthesis of arylquinones from quinones/hydroquinones
por: Dong, Yu, et al.
Publicado: (2022)

O(2)-Mediated Dehydrogenative Phenoxazination of Phenols
por: Benchouaia, Rajaa, et al.
Publicado: (2022)

Construction of trisubstituted chromone skeletons carrying electron-withdrawing groups via PhIO-mediated dehydrogenation and its application to the synthesis of frutinone A
por: Li, Qiao, et al.
Publicado: (2019)

Unified synthesis of mono/bis-arylated phenols via Rh(III)-catalyzed dehydrogenative coupling
por: Wu, Qian, et al.
Publicado: (2017)

Crystal structure of 12-benzylsulfanyl-2,9-dibromo-6H-dibenzo[b,g][1,8]naphthyridin-11-one
por: Resch, Sebastian, et al.
Publicado: (2015)

Cu‐Catalyzed Cross‐Dehydrogenative ortho‐Aminomethylation of Phenols
por: Yu, Congjun, et al.
Publicado: (2018)

Cross dehydrogenative C–O coupling catalysed by a catenane-coordinated copper(i)
por: Zhu, Lihui, et al.
Publicado: (2020)

A walk around the application of nanocatalysts for cross-dehydrogenative coupling of C–H bonds
por: Wang, Jianjie, et al.
Publicado: (2019)

Metal‐ and Reagent‐Free Electrochemical Synthesis of Alkyl Arylsulfonates in a Multi‐Component Reaction
por: Blum, Stephan P., et al.
Publicado: (2020)

Cross-dehydrogenative N–N couplings
por: Tabey, Alexis, et al.
Publicado: (2021)

Pollutant Adsorbtion and Detection: Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane (Global Challenges 8/2018)
por: Ryvlin, Dimitrij, et al.
Publicado: (2018)

Methyl‐Substituted α‐Cyclodextrin as Affinity Material for Storage, Separation, and Detection of Trichlorofluoromethane
por: Ryvlin, Dimitrij, et al.
Publicado: (2018)

PtO(2)/PTSA system catalyzed regioselective hydration of internal arylalkynes bearing electron withdrawing groups
por: Lin, Hsin-Ping, et al.
Publicado: (2018)

Metal‐Free Electrochemical Synthesis of Sulfonamides Directly from (Hetero)arenes, SO(2), and Amines
por: Blum, Stephan P., et al.
Publicado: (2021)

Metal-free oxidative cross-dehydrogenative coupling of quinones with benzylic C(sp(3))–H bonds
por: Dong, Yu, et al.
Publicado: (2019)

Iron-catalyzed α-C–H functionalization of π-bonds: cross-dehydrogenative coupling and mechanistic insights
por: Wang, Yidong, et al.
Publicado: (2020)

Metal‐Free Twofold Electrochemical C−H Amination of Activated Arenes: Application to Medicinally Relevant Precursor Synthesis
por: Wesenberg, Lars J., et al.
Publicado: (2020)

Electrochemical Dehydrogenative C(sp(2))−H Amination
por: Puthanveedu, Mahesh, et al.
Publicado: (2021)

Cobalt‐Catalyzed Dehydrogenative C−H Silylation of Alkynylsilanes
por: Stachowiak, Hanna, et al.
Publicado: (2021)

Non-noble metal-catalyzed cross-dehydrogenation coupling (CDC) involving ether α-C(sp(3))–H to construct C–C bonds
por: Yu, Hui, et al.
Publicado: (2023)

Unexpected high robustness of electrochemical cross-coupling for a broad range of current density
por: Wiebe, Anton, et al.
Publicado: (2017)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Copper-catalyzed diastereoselective aerobic intramolecular dehydrogenative coupling of hydrazones via sp(3) C–H functionalization
por: Wu, Xuesong, et al.
Publicado: (2015)

Copper-mediated construction of benzothieno[3,2-b]benzofurans by intramolecular dehydrogenative C–O coupling reaction
por: Ai, Liankun, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_e0kf5sur556sr7qk8o96j3b1h5