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Metal‐Free Aryl Cross‐Coupling Directed by Traceless Linkers

The metal‐free, highly selective synthesis of biaryls poses a major challenge in organic synthesis. The scope and mechanism of a promising new approach to (hetero)biaryls by the photochemical fusion of aryl substituents tethered to a traceless sulfonamide linker (photosplicing) are reported. Interro...

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Detalles Bibliográficos
Autores principales: Haensch, Veit G., Neuwirth, Toni, Steinmetzer, Johannes, Kloss, Florian, Beckert, Rainer, Gräfe, Stefanie, Kupfer, Stephan, Hertweck, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973076/
https://www.ncbi.nlm.nih.gov/pubmed/31621964
http://dx.doi.org/10.1002/chem.201903582