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Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction

Azoheteroarene photoswitches have attracted attention due to their unique properties. We present the stationary photochromism and ultrafast photoisomerization mechanism of thiophenylazobenzene (TphAB). It demonstrates impressive fatigue resistance and photoisomerization efficiency, and shows favorab...

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Detalles Bibliográficos
Autores principales: Slavov, Chavdar, Yang, Chong, Heindl, Andreas H., Wegner, Hermann A., Dreuw, Andreas, Wachtveitl, Josef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973119/
https://www.ncbi.nlm.nih.gov/pubmed/31595575
http://dx.doi.org/10.1002/anie.201909739