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Thiophenylazobenzene: An Alternative Photoisomerization Controlled by Lone‐Pair⋅⋅⋅π Interaction
Azoheteroarene photoswitches have attracted attention due to their unique properties. We present the stationary photochromism and ultrafast photoisomerization mechanism of thiophenylazobenzene (TphAB). It demonstrates impressive fatigue resistance and photoisomerization efficiency, and shows favorab...
Autores principales: | Slavov, Chavdar, Yang, Chong, Heindl, Andreas H., Wegner, Hermann A., Dreuw, Andreas, Wachtveitl, Josef |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973119/ https://www.ncbi.nlm.nih.gov/pubmed/31595575 http://dx.doi.org/10.1002/anie.201909739 |
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